Hydrothermal synthesis and characterization of bimetallic cluster complex [{Mn(phen)(2)}(2)V4O12]center dot 1/2 H2O
文献类型:期刊论文
作者 | Lu Y ; Wang EB ; Yuan M ; Li YG ; Xu L ; Hu CW ; Hu NH ; Jia HQ |
刊名 | solid state sciences |
出版日期 | 2002 |
卷号 | 4期号:4页码:449-453 |
ISSN号 | 1293-2558 |
关键词 | MOLYBDENUM PHOSPHATE HYBRID MATERIALS OXIDES TUNNEL |
通讯作者 | wang eb |
中文摘要 | a new bimetallic cluster complex with the formula [(mn(phen)(2))(2)v4o12].1/2 h2o has been synthesized through hydrothermal reaction of vanadate staring material with manganese cation in the presence of nitrogen donor chelating ligand and characterized by single-crystal x-ray diffraction, elemental analysis, ir uv-vis, esr spectrum and thermal analysis. the compound crystallize in the monoclinic space group p2(1)/c with a = 18.475(4) angstrom, b = 11.473(2) angstrom, c = 23.667(5) angstrom, beta = 97.76(3)degrees, v = 4971(2) angstrom(3) and z = 4. the structure of [{mn(phen)(2)}(2)v4o12].1/2 h2o is composed of a discrete v4o124- cluster covalently attached to two [mn(phen)(2)](2+) fragments. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000175251200002 |
公开日期 | 2010-11-03 |
源URL | [http://202.98.16.49/handle/322003/18639] |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Lu Y,Wang EB,Yuan M,et al. Hydrothermal synthesis and characterization of bimetallic cluster complex [{Mn(phen)(2)}(2)V4O12]center dot 1/2 H2O[J]. solid state sciences,2002,4(4):449-453. |
APA | Lu Y.,Wang EB.,Yuan M.,Li YG.,Xu L.,...&Jia HQ.(2002).Hydrothermal synthesis and characterization of bimetallic cluster complex [{Mn(phen)(2)}(2)V4O12]center dot 1/2 H2O.solid state sciences,4(4),449-453. |
MLA | Lu Y,et al."Hydrothermal synthesis and characterization of bimetallic cluster complex [{Mn(phen)(2)}(2)V4O12]center dot 1/2 H2O".solid state sciences 4.4(2002):449-453. |
入库方式: OAI收割
来源:长春应用化学研究所
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