Hydrothermal synthesis and crystal structure of an unusual compound: [Cu(en)(2)](4)[(SiMo8V4O40)-O-V((VO)-O-IV)(2)][MoO4](2)center dot 5H(2)O
文献类型：期刊论文
| 作者 | Luan GY ; Li YG ; Wang EB ; Han ZB ; Hu CW ; Hu NH ; Jia HQ |
| 刊名 | journal of solid state chemistry
 |
| 出版日期 | 2002 |
| 卷号 | 165期号:1页码:1-5 |
| 关键词 | POLYOXOMETALATE CHEMISTRY KEGGIN HETEROPOLYVANADATE POLYOXOANION POLYANION CLUSTERS CHAIN |
| ISSN号 | 0022-4596 |
| 通讯作者 | wang eb |
| 中文摘要 | a novel compound [cu(en)(2)](4)[(simo8v4o40)-o-v(v-iv o)(2)] [moo4](2) . 5h(2)o has been hydrothermally synthesized and structurally characterized by single-crystal x-ray diffraction. black crystals crystallize in the tetragonal. system, space group 14/m, a = b = 14.019(2) angstrom, c = 20.341(4) angstrom, v = 3997.9(11) angstrom(3), z = 2, lambda(mokalpha) = 0.71073 angstrom (r(f) = 0.0443 for 1819 reflections). data were collected on a siemens p4 four-circle diffractometer at 293 k in the range of 1.76 < theta < 24.98degrees using the omega-scan technique. the structure was solved by the direct method and refined by the full-matrix least squares on f-2 method using the shelxl-97 software. x-ray crystallographic study showed that the title compound contained a bicapped alpha-keggin fragment [simo8 (v4o40)-o-v((vo)-o-iv)(2)](4-) polyoxoanion. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000175169200001 |
| 公开日期 | 2010-11-03 |
| 源URL | [http://202.98.16.49/handle/322003/18653]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Luan GY,Li YG,Wang EB,et al. Hydrothermal synthesis and crystal structure of an unusual compound: [Cu(en)(2)](4)[(SiMo8V4O40)-O-V((VO)-O-IV)(2)][MoO4](2)center dot 5H(2)O[J]. journal of solid state chemistry,2002,165(1):1-5. |
| APA | Luan GY.,Li YG.,Wang EB.,Han ZB.,Hu CW.,...&Jia HQ.(2002).Hydrothermal synthesis and crystal structure of an unusual compound: [Cu(en)(2)](4)[(SiMo8V4O40)-O-V((VO)-O-IV)(2)][MoO4](2)center dot 5H(2)O.journal of solid state chemistry,165(1),1-5. |
| MLA | Luan GY,et al."Hydrothermal synthesis and crystal structure of an unusual compound: [Cu(en)(2)](4)[(SiMo8V4O40)-O-V((VO)-O-IV)(2)][MoO4](2)center dot 5H(2)O".journal of solid state chemistry 165.1(2002):1-5. |
入库方式： OAI收割
来源：长春应用化学研究所
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