Hydrothermal synthesis and X-ray single crystal structure of bimetallic cluster complex [{Co(phen)(2)}(2)V4O12]center dot H2O
文献类型：期刊论文
| 作者 | Lu Y ; Wang EB ; Yuan M ; Li YG ; Hu CW ; Hu NH ; Jia HQ |
| 刊名 | journal of molecular structure
 |
| 出版日期 | 2002 |
| 卷号 | 607期号:2-3页码:189-194 |
| ISSN号 | 0022-2860 |
| 关键词 | VANADIUM-OXIDE COORDINATION-COMPLEXES MOLYBDENUM PHOSPHATE POLYOXOANION TUNNEL |
| 通讯作者 | wang eb |
| 中文摘要 | a new bimetallic cluster complex with the formula [{co(phen)(2)}(2)v4o12](h2o)-h-. was synthesized from the hydrothermal reaction of v2o5, h2c2o4, co(no3)(2), 1,10-phenanthroline (phen), (c4h9)(4)noh and water. the compound crystallizes in an orthorhombic system with space group pbcn and unit cell parameters a = 19.106(3) angstrom, b = 15.250(3) angstrom, c = 16.321(2) angstrom, v = 4755.4(13) angstrom(3), z = 4 and r = 0.0318. the bimetallic cluster complex [{co(phen)(2)}(2)v4o12](h2o)-h-. is composed of a discrete v4o124- cluster eovalently attached to two [co(phen)(2)](2+) fragments and the discrete hexanuclear bimetallic clusters of [{co(phen)(2)}(v4o12)-v-2](h2o)-h-. are further extended into interesting three-dimensional supermolecular arrays via pi-pi stacking interactions of phen groups. other characterizations by elemental analysis, ir, and thermal analysis are also described. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000174630100012 |
| 公开日期 | 2010-11-03 |
| 源URL | [http://202.98.16.49/handle/322003/18697]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lu Y,Wang EB,Yuan M,et al. Hydrothermal synthesis and X-ray single crystal structure of bimetallic cluster complex [{Co(phen)(2)}(2)V4O12]center dot H2O[J]. journal of molecular structure,2002,607(2-3):189-194. |
| APA | Lu Y.,Wang EB.,Yuan M.,Li YG.,Hu CW.,...&Jia HQ.(2002).Hydrothermal synthesis and X-ray single crystal structure of bimetallic cluster complex [{Co(phen)(2)}(2)V4O12]center dot H2O.journal of molecular structure,607(2-3),189-194. |
| MLA | Lu Y,et al."Hydrothermal synthesis and X-ray single crystal structure of bimetallic cluster complex [{Co(phen)(2)}(2)V4O12]center dot H2O".journal of molecular structure 607.2-3(2002):189-194. |
入库方式： OAI收割
来源：长春应用化学研究所
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