Hydrothermal synthesis, crystal structure and properties of [HPDA][H(2)PDA](2)[As-2(III)-AsMo8V4O40]center dot 3H(2)O (PDA = propane diamine)
文献类型：期刊论文
| 作者 | Luan GY ; Wang EB ; Han ZB ; Li YG ; Hu CW ; Hu NH ; Jia HQ |
| 刊名 | journal of molecular structure
 |
| 出版日期 | 2002 |
| 卷号 | 606期号:1-3页码:211-215 |
| 关键词 | TRANSFERABLE BUILDING-BLOCKS POLYOXOMETALATE CHEMISTRY KEGGIN HETEROPOLYANION DIMENSIONS POLYANION FRAGMENTS CLUSTERS ANIONS |
| ISSN号 | 0022-2860 |
| 通讯作者 | wang eb |
| 中文摘要 | [nh3ch2ch2ch2nh2][nh3ch2ch2ch2nh3](2)[(as2asmo8v4o40)-as-iii-mo-v-o-iv].3h(2)o was hydrothermally synthesized and structurally characterized by single crystal x-ray diffraction. crystal data: monoclinic, c2/c, a = 45.375(9) angstrom, b = 11.774(2) angstrom, c = 23.438(5) angstrom, beta = 96.62(3)degrees. x-ray crystallographic study showed that the crystal structure was constructed by bicapped alpha-keggin fragments [(as2asmo8v4o40)-as-iii-mo-v-o-iv](5-) polyoxoanion. the title compound had a high catalytic activity for the oxidation of benzaldehyde to benzoic acid using h2o2 as oxidant in a liquid-solid biphase system. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000174334700022 |
| 公开日期 | 2010-11-03 |
| 源URL | [http://202.98.16.49/handle/322003/18715]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Luan GY,Wang EB,Han ZB,et al. Hydrothermal synthesis, crystal structure and properties of [HPDA][H(2)PDA](2)[As-2(III)-AsMo8V4O40]center dot 3H(2)O (PDA = propane diamine)[J]. journal of molecular structure,2002,606(1-3):211-215. |
| APA | Luan GY.,Wang EB.,Han ZB.,Li YG.,Hu CW.,...&Jia HQ.(2002).Hydrothermal synthesis, crystal structure and properties of [HPDA][H(2)PDA](2)[As-2(III)-AsMo8V4O40]center dot 3H(2)O (PDA = propane diamine).journal of molecular structure,606(1-3),211-215. |
| MLA | Luan GY,et al."Hydrothermal synthesis, crystal structure and properties of [HPDA][H(2)PDA](2)[As-2(III)-AsMo8V4O40]center dot 3H(2)O (PDA = propane diamine)".journal of molecular structure 606.1-3(2002):211-215. |
入库方式： OAI收割
来源：长春应用化学研究所
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