Photochemical synthesis, properties and X-ray crystal structure of tetrabutylammonium dodecamolybdophosphate heteropoly blue
文献类型：期刊论文
| 作者 | Liu SZ ; Li JP ; Feng XH ; Zhang ZW ; Chen JY ; Wang Z ; Xing Y ; Jia HQ ; Lin YH |
| 刊名 | chinese journal of chemistry
 |
| 出版日期 | 2002 |
| 卷号 | 20期号:3页码:240-246 |
| ISSN号 | 1001-604x |
| 通讯作者 | liu sz |
| 中文摘要 | the title heteropoly blue, (bu4n)(6)h-10 [(pmo11moo40)-mo-vi-o-v](4) . h2o has been photochemically synthesized and characterized with elemental analysis, solid diffusion reflectance electronic spectra, cv, esr, xps, ir spectra, conductivity measurement and x-ray single crystal analysis. the crystallographic data for c96h218mo48n6o169p4 are as follows: m-r = 8889.76, triclinic, p (1) over bar, a = 1.4142 (3) nm, b = 2.6027 (5) nm, c = 2.6403(5) nm, alpha = 113.96(3)degrees, beta = 90.05(3)degrees, gamma = 105.71(3)degrees, v = 8.481 (3) nm(3), z = 1, d-c = 1.741 g/cm(3), f (000) = 4264, mu = 1.798 mm(-1). the x-ray crystal structure analysis reveals that there is one independent molecule in the unit cell of the title heteropoly blue which contains four mixed-valence heteropoly anions, six tetrabutylammonium cations and one water molecule. its molecular structure possesses a centrosymmetrical arrangement in the unit cell. the phosphorus atom is in the crystallographic inversion center of the heteropoly anion and the eight oxygen atoms surrounding central phosphorus atom comprise of a distorted hexahedron. heteropolyanion has two equal sets of po4 tetrahedron. the po4 tetrahedron and the moo6 octahedron in the polyanion are greatly distorted. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000174457700006 |
| 公开日期 | 2010-11-03 |
| 源URL | [http://202.98.16.49/handle/322003/18721]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu SZ,Li JP,Feng XH,et al. Photochemical synthesis, properties and X-ray crystal structure of tetrabutylammonium dodecamolybdophosphate heteropoly blue[J]. chinese journal of chemistry,2002,20(3):240-246. |
| APA | Liu SZ.,Li JP.,Feng XH.,Zhang ZW.,Chen JY.,...&Lin YH.(2002).Photochemical synthesis, properties and X-ray crystal structure of tetrabutylammonium dodecamolybdophosphate heteropoly blue.chinese journal of chemistry,20(3),240-246. |
| MLA | Liu SZ,et al."Photochemical synthesis, properties and X-ray crystal structure of tetrabutylammonium dodecamolybdophosphate heteropoly blue".chinese journal of chemistry 20.3(2002):240-246. |
入库方式： OAI收割
来源：长春应用化学研究所
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