Preparation and gas sensitivity of octa-n-butoxy-2,3-naphthalocyanine copper(II) Langmuir-Blodgett film
文献类型:期刊论文
作者 | He CY ; Huo LH ; Wu YQ ; Zuo X ; Xi SQ |
刊名 | chemical journal of chinese universities-chinese
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出版日期 | 2002 |
卷号 | 23期号:1页码:14-17 |
关键词 | ELECTRICAL-CONDUCTIVITY CHANGES PHTHALOCYANINE |
ISSN号 | 0251-0790 |
通讯作者 | wu yq |
中文摘要 | the formation process of monolayer of octa-n-butoxy-2,3-naphthalocyanine copper ( i), [cunc(obu)(8)], on water subphase was studied. its multilayers were successifully deposited on the hydrophilic substrates by z-type deposition mode using lb technique. stable solid film with a limiting molecular area of 0.74 nm(2) and a collapse pressure of 55 mn/m were formed. the lb film structure was characterized by ir and electronic absorption spectra. macrocycle of cunc (obu)(8) molecules have a face-to-face arrangement in the multilayers. these films have good sensitivities to vapor of alcohols, with the following sequence of sensitivities: i-proh>etoh>meoh. the response time and recovery time of the lb films to vapor of meoh, etoh and i-proh[volume fraction (1-5) x 10(-5)] were within 2 and 5 seconds respectively, while those of the lb films to ammonia(1 x 10(-4)) were 30-60 seconds and 4-5 minutes respectively. |
收录类别 | SCI收录期刊论文 |
语种 | 中文 |
WOS记录号 | WOS:000173834700004 |
公开日期 | 2010-11-03 |
源URL | [http://202.98.16.49/handle/322003/18791] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | He CY,Huo LH,Wu YQ,et al. Preparation and gas sensitivity of octa-n-butoxy-2,3-naphthalocyanine copper(II) Langmuir-Blodgett film[J]. chemical journal of chinese universities-chinese,2002,23(1):14-17. |
APA | He CY,Huo LH,Wu YQ,Zuo X,&Xi SQ.(2002).Preparation and gas sensitivity of octa-n-butoxy-2,3-naphthalocyanine copper(II) Langmuir-Blodgett film.chemical journal of chinese universities-chinese,23(1),14-17. |
MLA | He CY,et al."Preparation and gas sensitivity of octa-n-butoxy-2,3-naphthalocyanine copper(II) Langmuir-Blodgett film".chemical journal of chinese universities-chinese 23.1(2002):14-17. |
入库方式: OAI收割
来源:长春应用化学研究所
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