Synthesis and characterization of tris(cyclopentylcyclopentadienyl)lanthanide complexes (C5H9C5H4)(3)NdBrLi(THF)(3) and (C5H9C5H4)(3)SmTHF
文献类型：期刊论文
| 作者 | Cui DM ; Cheng JH ; Zhuang XL ; Hu NH ; Jin JZ ; Chen WQ ; Tang T ; Huang BT |
| 刊名 | chinese journal of structural chemistry
 |
| 出版日期 | 2002 |
| 卷号 | 21期号:1页码:78-82 |
| 关键词 | RAY CRYSTAL-STRUCTURE COORDINATION |
| ISSN号 | 0254-5861 |
| 通讯作者 | cui dm |
| 中文摘要 | (c5h9c5h4)(3)ndbrli(thf)(4)(1)(c5h9=cyclopentyl) was obtained from the reaction of ndcl3 with c5h9c5h4na and libr (nd:na:li=1:2:1 molar ratio) in the x-ray crystallography showed that the ten-coordinated neodymium atom is bonded to three cyclopentylcyclopentadienyl(eta(5)) rings and a single bromine atom bridging a lithium which is bonded to three thf molecules. complex 1 is triclinic, p1 space group with unit dimensions of a= 12.048(2), b= 13.498(3), c= 13.831(3)angstrom, a = 104.16(3), beta = 104.07(3), gamma =95.96(3)degrees, v=2083.3(7)angstrom(3), z=2, d-c=1.35mg/m(3) and f(000)=874. (c5h9c5h4)(3)smthf (2) was synthesized by reaction of anhydrous smcl3 with c5h9c5h4na at a molar ratio of 1:3. the structure was determined by x-ray crystallography. the ten-coordinated samarium atom is bonded to three cycloperrtylcyclopentadienyl rings and one oxygen of thf molecule to form a pseudo-tetrahedron. complex 2 is orthorhombic, fdd2 space group with unit cell dimensions of a =28.175(5)angstrom, b =46.24(2) angstrom, c =9.167(4) angstrom(3), v=11943(8)angstrom(3), z= 16, d-c = 1.38mg/m(3) and f(000)=5136. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 中文 |
| WOS记录号 | WOS:000173491300017 |
| 公开日期 | 2010-11-03 |
| 源URL | [http://202.98.16.49/handle/322003/18813]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Cui DM,Cheng JH,Zhuang XL,et al. Synthesis and characterization of tris(cyclopentylcyclopentadienyl)lanthanide complexes (C5H9C5H4)(3)NdBrLi(THF)(3) and (C5H9C5H4)(3)SmTHF[J]. chinese journal of structural chemistry,2002,21(1):78-82. |
| APA | Cui DM.,Cheng JH.,Zhuang XL.,Hu NH.,Jin JZ.,...&Huang BT.(2002).Synthesis and characterization of tris(cyclopentylcyclopentadienyl)lanthanide complexes (C5H9C5H4)(3)NdBrLi(THF)(3) and (C5H9C5H4)(3)SmTHF.chinese journal of structural chemistry,21(1),78-82. |
| MLA | Cui DM,et al."Synthesis and characterization of tris(cyclopentylcyclopentadienyl)lanthanide complexes (C5H9C5H4)(3)NdBrLi(THF)(3) and (C5H9C5H4)(3)SmTHF".chinese journal of structural chemistry 21.1(2002):78-82. |
入库方式： OAI收割
来源：长春应用化学研究所
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