Preparation and characterization of PSt-b-PHEMA metal hybrids
文献类型:期刊论文
作者 | Wang YM ; Wu JS ; Yuan JY ; Sun GF ; Pan CY |
刊名 | journal of applied polymer science
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出版日期 | 2002 |
卷号 | 83期号:13页码:2883-2891 |
关键词 | POLY(STYRENE-B-2-VINYL PYRIDINE) FILM SEMICONDUCTOR-POLYMER COMPOSITES TRANSFER RADICAL POLYMERIZATION COLLOIDAL SILVER SIZE CONTROL MICRODOMAINS NANOPARTICLES MICROSPHERES IONOMERS |
ISSN号 | 0021-8995 |
通讯作者 | wang ym |
中文摘要 | the block copolymer polystyrene-b-poly[2-(trimethylsilyloxy)ethylene methacrylate] (pst-b-ptmsema) was synthesized using atom-transfer radical polymerization (atrp). the hydrolysis of pst-b-ptmsema led to the formation of an amphiphilic block copolymer, polystyrene-b-poly(2-hydroxylethyl methacrylate) (pst-b-phema), which was characterized by gpc and h-1-nmr. tem showed that the pst-b-phema formed a micelle, which is pst as the core and phema as the shell. under appropriate conditions, the nickel or cobalt ion cause chemical reactions in these micelles and could be reduced easily. esca analysis showed that before reduction the metal existed as a hydroxide; after reduction, the metal existed as an oxide, and the metal content of these materials on the surface is more than that on the surface of the copolymer metal ion. xrd analysis showed that the metal existed as a hydroxide before reduction and existed as a metal after reduction. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000173408100018 |
公开日期 | 2010-11-03 |
源URL | [http://202.98.16.49/handle/322003/18835] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Wang YM,Wu JS,Yuan JY,et al. Preparation and characterization of PSt-b-PHEMA metal hybrids[J]. journal of applied polymer science,2002,83(13):2883-2891. |
APA | Wang YM,Wu JS,Yuan JY,Sun GF,&Pan CY.(2002).Preparation and characterization of PSt-b-PHEMA metal hybrids.journal of applied polymer science,83(13),2883-2891. |
MLA | Wang YM,et al."Preparation and characterization of PSt-b-PHEMA metal hybrids".journal of applied polymer science 83.13(2002):2883-2891. |
入库方式: OAI收割
来源:长春应用化学研究所
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