Gas transport properties of a series of cardo polyarylethers
文献类型:期刊论文
作者 | Wang ZG ; Chen TL ; Xu JP |
刊名 | journal of applied polymer science
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出版日期 | 2002 |
卷号 | 83期号:4页码:791-801 |
关键词 | SYMMETRY POLYSULFONES MEMBRANES |
ISSN号 | 0021-8995 |
通讯作者 | wang zg |
中文摘要 | gas transport of h-2, co2, o-2, n-2, and ch4 in a series of cardo polyarylethers were examined over a temperature range of 30 similar to 100 degreesc. these polymers include three poly(aryletherketone)s, two poly(arylethersulfone)s, and one poly(aryletherketoneketone). it was found that the large length/diameter ratio of the polymer repeat unit for cardo polyaryletherketoneketone (pekk-c) and strong intermolecular interaction in hydrogen-bonded polyarylethersulfone (pes-h) and hydrogen-bonded polyaryletherketone (pek-h) resulted in a considerable increase in gas permselectivity. alkyl-substituted polyaryletherketone (pek-a), bearing a pendant bulky propyl group on the cardo ring, simultaneously exhibited 62.5% higher h-2 permeability and 59.8% higher h-2/n-2 permselectivity than unmodified poly(aryletherketone) (pek-c). the causes of the trend were interpreted in terms of chain packing density, segmental motion ability, steric factor, and intermolecular interaction of polymers, together with gas kinetic diameter and critical temperature data. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000172426900010 |
公开日期 | 2010-11-03 |
源URL | [http://202.98.16.49/handle/322003/18873] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Wang ZG,Chen TL,Xu JP. Gas transport properties of a series of cardo polyarylethers[J]. journal of applied polymer science,2002,83(4):791-801. |
APA | Wang ZG,Chen TL,&Xu JP.(2002).Gas transport properties of a series of cardo polyarylethers.journal of applied polymer science,83(4),791-801. |
MLA | Wang ZG,et al."Gas transport properties of a series of cardo polyarylethers".journal of applied polymer science 83.4(2002):791-801. |
入库方式: OAI收割
来源:长春应用化学研究所
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