Study on the kinetics of ferrocene derivatives in polymer electrolyte/electrode interface at microelectrode
文献类型：期刊论文
| 作者 | Gu NY ; Zhou HF ; Ding LM ; Shi Z ; Dong SJ |
| 刊名 | solid state ionics
 |
| 出版日期 | 2000 |
| 卷号 | 138期号:1-2页码:123-133 |
| 关键词 | ELECTRON-TRANSFER RATE MICRODISK ELECTRODES HETEROGENEOUS KINETICS POLY(ETHYLENE OXIDE) DIFFUSION VOLTAMMETRY CHRONOAMPEROMETRY POLYELECTROLYTE VOLTAMMOGRAMS DEPENDENCE |
| ISSN号 | 0167-2738 |
| 通讯作者 | dong sj |
| 中文摘要 | heterogeneous electron transfer rate constants (k(s)) and diffusion coefficients (d) of the ferrocene and its derivatives. in a new synthetic comb polymer solvent, poly(dimethylsiloxane-g-monomethylether polyethylene glycol) (scp), and several other polymer solvents were estimated by using microelectrodes. also, the influence of various supporting electrolytes on k(s) and d of ferrocene was studied. it was shown that k(s) and d of ferrocene decreased with increasing anionic size of the supporting electrolyte, but k(s) tended to increase with increasing radius of the solvated cation. also, the cationic size of the supporting electrolytes had little effects on d. the values of k(s) and d for the ferrocene derivatives in the polymer solvents were in sharp contrast to those in monomeric solvents. thus. the k(s) values were proportional to d in the polymer solvents. which indicates that solvent dynamics control of the electrode reaction. the values of k(s) and d of ferrocene in scp were larger than those in other polymer solvents indicating that scp is a good polymer solvent. (c) 2000 elsevier science b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000166532300012 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/19383]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Gu NY,Zhou HF,Ding LM,et al. Study on the kinetics of ferrocene derivatives in polymer electrolyte/electrode interface at microelectrode[J]. solid state ionics,2000,138(1-2):123-133. |
| APA | Gu NY,Zhou HF,Ding LM,Shi Z,&Dong SJ.(2000).Study on the kinetics of ferrocene derivatives in polymer electrolyte/electrode interface at microelectrode.solid state ionics,138(1-2),123-133. |
| MLA | Gu NY,et al."Study on the kinetics of ferrocene derivatives in polymer electrolyte/electrode interface at microelectrode".solid state ionics 138.1-2(2000):123-133. |
入库方式： OAI收割
来源：长春应用化学研究所
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