Synthesis, structure and ring-opening polymerization of phenolphthalein macrocyclic polyarylates
文献类型：期刊论文
| 作者 | Jiang HY ; Qi YH ; Chen TL ; Bo SQ ; Ding MX ; Gao LX ; Xu JP ; He TB ; Zhang Y |
| 刊名 | macromolecular chemistry and physics
 |
| 出版日期 | 2000 |
| 卷号 | 201期号:17页码:2385-2393 |
| 关键词 | ARYLENE ETHER SULFONE THIOETHER KETONE OLIGOMERS 1 CYCLIC OLIGOMERS FACILE POLYMERIZATION AROMATIC MACROCYCLES CARDO POLYESTERS BISPHENOL-A PRECURSORS TRANSPORT 2-DIBENZOYLBENZENE MOIETY |
| ISSN号 | 1022-1352 |
| 通讯作者 | chen tl |
| 中文摘要 | phenolphthalein based polyarylate macrocyclic oligomers were selectively synthesized by an interfacial polycondensation reaction of o-phthaloyl dichloride with phenolphthalein. the high selectivity benefits from the role of phenolphthalein as a color indicator, an efficient phase transfer catalyst, acid a preferred conformation of the starting materials as indicated by analyzing a single-crystal x-ray structure of an analogous macrocycle. the melt rop of phenolphthalein polyarylate cyclic dimer was studied using nucleophilic initiators, the molecular weight of the resulting polymers builds up very rapidly at the very early stage of polymerization but decreases with time. during the rop of cyclic dimer, analogous macrocycles with higher degree of polymerization (n greater than or equal to 3) and linear oligomers were produced by backbiting reaction especially at later stage of polymerization. conversion of cyclic dimer is very fast at the earlier stage of polymerization and then increases slowly with time as analyzed by gel permeation chromatography. however, the total amount of cyclic oligomers in the rop system increases with time at the later stage of polymerization because of the formation of larger macrocycles. the resulting polymers are amorphous. glass transition temperatures (t(g)s) of these polymers are influenced by the polymerization time, type of initiator, and initiator concentration. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000165954600024 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/19405]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Jiang HY,Qi YH,Chen TL,et al. Synthesis, structure and ring-opening polymerization of phenolphthalein macrocyclic polyarylates[J]. macromolecular chemistry and physics,2000,201(17):2385-2393. |
| APA | Jiang HY.,Qi YH.,Chen TL.,Bo SQ.,Ding MX.,...&Zhang Y.(2000).Synthesis, structure and ring-opening polymerization of phenolphthalein macrocyclic polyarylates.macromolecular chemistry and physics,201(17),2385-2393. |
| MLA | Jiang HY,et al."Synthesis, structure and ring-opening polymerization of phenolphthalein macrocyclic polyarylates".macromolecular chemistry and physics 201.17(2000):2385-2393. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。