Synthesis and structure of molybdenum-citrato cluster mu(2)-S bridge
文献类型：期刊论文
| 作者 | Li DM ; Li YF ; Xing YH ; Wang RZ ; Liu SQ ; Sun HR ; Wang TG ; Xu JQ ; Xing Y ; Lin YH ; Jia HQ |
| 刊名 | chemical journal of chinese universities-chinese
 |
| 出版日期 | 2000 |
| 卷号 | 21期号:10页码:1464-1467 |
| 关键词 | RAY CRYSTAL-STRUCTURE IRON PROTEIN COMPLEX NITROGENASE COORDINATION LIGAND |
| ISSN号 | 0251-0790 |
| 通讯作者 | xu jq |
| 中文摘要 | a new molybdenum-citrato cluster containing [mo2o2(mu-s)(2)(c6h5o7)(c6h4o7)](5-) anion was synthesized and characterized by elemental analysis, ir, uv-vis spectra, xps and x-ray diffraction. the parameters of the crystal structure of the compound are monoclinic, space group p2(1)/c, a = 2. 376 6(5) nm, b = 1. 327 4(3) nm, c = 2. 247 1(5) nm, beta = 118. 21 degrees, v = 6. 247(2) nm(3), z = 8, d-c = 2. 128 g/cm(3), f(000) = 3 984, mu = 1 694 cm(-1), r = 0. 083 1 and r-2,r-w = 0. 154 9. the anion is binuclear molybdenum-citrato complex with mu(2)-s bridge. each molybdenum atom pocesesses a distorted octahedral struture, which is coordinated with a terminal oxygen, two sulfur atoms, three oxygen atoms of hydroxyl, alpha-carboxylate, beta-carboxylate from citrate. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 中文 |
| WOS记录号 | WOS:000089885400004 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/19523]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li DM,Li YF,Xing YH,et al. Synthesis and structure of molybdenum-citrato cluster mu(2)-S bridge[J]. chemical journal of chinese universities-chinese,2000,21(10):1464-1467. |
| APA | Li DM.,Li YF.,Xing YH.,Wang RZ.,Liu SQ.,...&Jia HQ.(2000).Synthesis and structure of molybdenum-citrato cluster mu(2)-S bridge.chemical journal of chinese universities-chinese,21(10),1464-1467. |
| MLA | Li DM,et al."Synthesis and structure of molybdenum-citrato cluster mu(2)-S bridge".chemical journal of chinese universities-chinese 21.10(2000):1464-1467. |
入库方式： OAI收割
来源：长春应用化学研究所
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