1,1 '-di(tert-butyl)metallocenium cations. The x-ray crystal structures of [M((C5H4Bu)-Bu-t)(2)]PF6 (M = Fe, Co) and [Co((C5H4Bu)-Bu-t)(2)](2)CoCl4
文献类型：期刊论文
| 作者 | Herberhold M ; Cheng YX ; Jin GX ; Milius W |
| 刊名 | zeitschrift fur naturforschung section b-a journal of chemical sciences
 |
| 出版日期 | 2000 |
| 卷号 | 55期号:9页码:814-820 |
| 关键词 | MOLECULAR-STRUCTURE NMR-SPECTROSCOPY DECAMETHYLFERROCENIUM 7 PARAMAGNETIC-COMPLEXES SUBSTITUTED FERROCENES BEHAVIOR METAL DIFFRACTION CHEMISTRY SPECTRA 7 8 8-TETRACYANO-PARA-QUINODIMETHANIDE |
| ISSN号 | 0932-0776 |
| 通讯作者 | herberhold m |
| 中文摘要 | the hexafluorophosphate salts [fe((c5h4bu)-bu-t)(2)]pf6 (1) and [co((c5h4bu)-bu-t)(2)]pf6 (2) crystallize in isotypic structures with centrosymmetric cations which have a staggered (transoid) conformation of the exactly parallel ring ligands (conformational angle tau = 180 degrees). the tetrachlorocobaltate salt, [co((c5h4bu)-bu-t)(2)](2)cocl4 (3), contains one almost eclipsed (tau = 140.4 degrees) and one almost staggered (tau = 101.4 degrees) cobaltocenium cation; in both cases, the cyclopentadienyl ring planes are slightly inclined (by alpha = 5.4 degrees and 4.1 degrees, respectively) to give more room to the tert-butyl substituents which are bent away from the metal in all three complexes 1 - 3. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000089699700005 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/19537]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Herberhold M,Cheng YX,Jin GX,et al. 1,1 '-di(tert-butyl)metallocenium cations. The x-ray crystal structures of [M((C5H4Bu)-Bu-t)(2)]PF6 (M = Fe, Co) and [Co((C5H4Bu)-Bu-t)(2)](2)CoCl4[J]. zeitschrift fur naturforschung section b-a journal of chemical sciences,2000,55(9):814-820. |
| APA | Herberhold M,Cheng YX,Jin GX,&Milius W.(2000).1,1 '-di(tert-butyl)metallocenium cations. The x-ray crystal structures of [M((C5H4Bu)-Bu-t)(2)]PF6 (M = Fe, Co) and [Co((C5H4Bu)-Bu-t)(2)](2)CoCl4.zeitschrift fur naturforschung section b-a journal of chemical sciences,55(9),814-820. |
| MLA | Herberhold M,et al."1,1 '-di(tert-butyl)metallocenium cations. The x-ray crystal structures of [M((C5H4Bu)-Bu-t)(2)]PF6 (M = Fe, Co) and [Co((C5H4Bu)-Bu-t)(2)](2)CoCl4".zeitschrift fur naturforschung section b-a journal of chemical sciences 55.9(2000):814-820. |
入库方式： OAI收割
来源：长春应用化学研究所
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