A study of resonance electron capture ionization on a quadrupole tandem mass spectrometer
文献类型:期刊论文
作者 | Wei JH ; Liu SY ; Fedoreyev SA ; Voinov VG |
刊名 | rapid communications in mass spectrometry
![]() |
出版日期 | 2000 |
卷号 | 14期号:18页码:1689-1694 |
关键词 | CHARGE-REMOTE FRAGMENTATIONS FAST-ATOM-BOMBARDMENT FATTY-ACIDS FLAVONOIDS DIFFERENTIATION ESTERS |
ISSN号 | 0951-4198 |
通讯作者 | liu sy |
中文摘要 | procedures that allow the realization of resonance electron capture (rec) mode on a commercial triple-quadrupole mass spectrometer, after some simple modifications, are described, rec mass spectrometry (ms) and tandem mass spectrometry (ms/ms) experiments were performed and spectra for some compounds were recorded. in particular, the charge-remote fragmentation (crf) spectra of [m - h](-) ions of docosanoic and docosenoic acids under low-energy collisionally activated dissociation (cad) conditions were obtained, and showed that there were no significant differences for [m - h](-) ions produced at different resonances (i,e. for [m - h](-) ions with different structures). this observation was explained on the basis of results obtained from deuterium-labeled fatty acids, which showed that different crf ions (but with the same m/z value in the absence of labels) could be produced by different mechanisms, and all of them were obviously realized under cad conditions that made spectra practically indistinguishable. the other example, which compared the rec-ms/ms spectrum of [m - h](-) ions and ei-ms/ms spectrum of m+. ions of daidzein, demonstrated the potential of the rec-ms/ms technique for more complex structure elucidation. copyright (c) 2000 john wiley & sons, ltd. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000089415000009 |
公开日期 | 2010-11-04 |
源URL | [http://202.98.16.49/handle/322003/19567] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Wei JH,Liu SY,Fedoreyev SA,et al. A study of resonance electron capture ionization on a quadrupole tandem mass spectrometer[J]. rapid communications in mass spectrometry,2000,14(18):1689-1694. |
APA | Wei JH,Liu SY,Fedoreyev SA,&Voinov VG.(2000).A study of resonance electron capture ionization on a quadrupole tandem mass spectrometer.rapid communications in mass spectrometry,14(18),1689-1694. |
MLA | Wei JH,et al."A study of resonance electron capture ionization on a quadrupole tandem mass spectrometer".rapid communications in mass spectrometry 14.18(2000):1689-1694. |
入库方式: OAI收割
来源:长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。