Gas transport properties of novel cardo poly(aryl ether ketone)s with pendant alkyl groups
文献类型：期刊论文
| 作者 | Wang ZG ; Chen TL ; Xu JP |
| 刊名 | macromolecules
 |
| 出版日期 | 2000 |
| 卷号 | 33期号:15页码:5672-5679 |
| 关键词 | PERMEATION BEHAVIOR MEMBRANES SEPARATION POLYMERS POLYCARBONATES PERMEABILITY SYMMETRY SORPTION SERIES |
| ISSN号 | 0024-9297 |
| 通讯作者 | wang zg |
| 中文摘要 | gas transport of hydrogen, oxygen, nitrogen, carbon dioxide, and methane in four cardo poly(aryl ether ketone)s containing different alkyl substituents on the phenyl ring has been examined from 30 to 100 degrees c. the permeability, diffusivity, solubility, and their temperature dependency were studied by correlations with gas shape, size, and critical temperature as well as polymeric structural factors including glass transition, secondary transition, cohesive energy density, and free volume. the bulky, stiff cardo and alkyl groups in tetramethyl-substituted tmpek-c resulted in increased h-2 permeability (by 55%) and h-2/n-2 permselectivity (by 106%) relative to bisphenol a polysulfone (psf). moreover, the weak dependence of gas transport on temperature in tmpek-c made it maintain high permselectivities (alpha(h2/n2) in 68.3 and alpha(o2/n2) in 5.71) up to 100 degrees c, exhibiting potential for high-temperature gas separation applications. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000088453000054 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/19655]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang ZG,Chen TL,Xu JP. Gas transport properties of novel cardo poly(aryl ether ketone)s with pendant alkyl groups[J]. macromolecules,2000,33(15):5672-5679. |
| APA | Wang ZG,Chen TL,&Xu JP.(2000).Gas transport properties of novel cardo poly(aryl ether ketone)s with pendant alkyl groups.macromolecules,33(15),5672-5679. |
| MLA | Wang ZG,et al."Gas transport properties of novel cardo poly(aryl ether ketone)s with pendant alkyl groups".macromolecules 33.15(2000):5672-5679. |
入库方式： OAI收割
来源：长春应用化学研究所
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