Shear induced mixing/demixing: Blends of homopolymers, of homopolymers plus copolymers, and blends in solution
文献类型:期刊论文
作者 | An L ; Hinrichs A ; Horst R ; Krause C ; Wolf BA |
刊名 | macromolecular symposia
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出版日期 | 2000 |
卷号 | 149页码:75-79 |
关键词 | FLOWING POLYMER-SOLUTIONS PHASE-SEPARATION MISCIBILITY GAPS DIAGRAMS BEHAVIOR |
ISSN号 | 1022-1360 |
通讯作者 | horst r |
中文摘要 | shear may shift the phase boundary towards the homogeneous state (shear induced mixing, sim), or in the opposite direction (shear induced demixing, sid). sim is the typical behavior of mixtures of components of low molar mass and polymer solutions, sid can be observed with solutions of high molar mass polymers and polymer blends at higher shear rates. the typical sequence with increasing shear rate is sim, then occurrence of an isolated additional immiscible area (sld), melting of this island into the main miscibility gap, and finally sim again. a three phase line originates and ends in two critical end points. raising pressure increases the shear effects. for copolymer containing systems sid is sometimes observed at very low shear rates, preceding the just mentioned sequence of shear influences. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000086672700012 |
公开日期 | 2010-11-04 |
源URL | [http://202.98.16.49/handle/322003/19781] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | An L,Hinrichs A,Horst R,et al. Shear induced mixing/demixing: Blends of homopolymers, of homopolymers plus copolymers, and blends in solution[J]. macromolecular symposia,2000,149:75-79. |
APA | An L,Hinrichs A,Horst R,Krause C,&Wolf BA.(2000).Shear induced mixing/demixing: Blends of homopolymers, of homopolymers plus copolymers, and blends in solution.macromolecular symposia,149,75-79. |
MLA | An L,et al."Shear induced mixing/demixing: Blends of homopolymers, of homopolymers plus copolymers, and blends in solution".macromolecular symposia 149(2000):75-79. |
入库方式: OAI收割
来源:长春应用化学研究所
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