A chromic molybdenum phosphate with a tunnel structure: hydrothermal synthesis and structure of (NH3CH2CH2NH3)(2) center dot (NH3CH2CH2NH2)(3)center dot[NaCr2Mo12O30(PO4)(HPO4)(4)(H2PO4)(3)]center dot 6H(2)O
文献类型：期刊论文
| 作者 | Xu L ; Sun Y ; Wang E ; Shen E ; Liu Z ; Hu C ; Xing Y ; Lin Y ; Jia H |
| 刊名 | journal of molecular structure
 |
| 出版日期 | 2000 |
| 卷号 | 519页码:55-59 |
| 关键词 | CRYSTAL-STRUCTURE HETEROPOLY BLUE |
| ISSN号 | 0022-2860 |
| 通讯作者 | wang e |
| 中文摘要 | a chromic molybdenum phosphate, (nh3ch2ch2nh3)(2).(nh3ch2ch2nh2)(3).[nacr2mo12o30(po4)(hpo4)(3)]. 6h(2)o, involving molybdenum present in v oxidation, has been hydrothermally synthesized and structurally characterized by single crystal x-ray diffraction and ir spectrum. deep brown-red crystals are formed in the triclinic system, space group p (1) over bar, a = 12.067(2), b = 14.677(3), c = 21.290(2) angstrom, alpha = 80.940(10)degrees, beta = 82.960(10)degrees, gamma = 76.61(2)degrees. the structure of the title compound may be considered to be two [mo6o15(hpo4)(h2po4)(3)](5-) units bonded to a chromic atom, although several p-o groups are not protonated on account of coordination with a na+ cation. the one-dimensional tunnels were formed in the solid of the title compound. (c) 2000 elsevier science b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000085722800007 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/19851]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Xu L,Sun Y,Wang E,et al. A chromic molybdenum phosphate with a tunnel structure: hydrothermal synthesis and structure of (NH3CH2CH2NH3)(2) center dot (NH3CH2CH2NH2)(3)center dot[NaCr2Mo12O30(PO4)(HPO4)(4)(H2PO4)(3)]center dot 6H(2)O[J]. journal of molecular structure,2000,519:55-59. |
| APA | Xu L.,Sun Y.,Wang E.,Shen E.,Liu Z.,...&Jia H.(2000).A chromic molybdenum phosphate with a tunnel structure: hydrothermal synthesis and structure of (NH3CH2CH2NH3)(2) center dot (NH3CH2CH2NH2)(3)center dot[NaCr2Mo12O30(PO4)(HPO4)(4)(H2PO4)(3)]center dot 6H(2)O.journal of molecular structure,519,55-59. |
| MLA | Xu L,et al."A chromic molybdenum phosphate with a tunnel structure: hydrothermal synthesis and structure of (NH3CH2CH2NH3)(2) center dot (NH3CH2CH2NH2)(3)center dot[NaCr2Mo12O30(PO4)(HPO4)(4)(H2PO4)(3)]center dot 6H(2)O".journal of molecular structure 519(2000):55-59. |
入库方式： OAI收割
来源：长春应用化学研究所
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