New insight into melting and crystallization behavior in semicrystalline poly(ethylene terephthalate)
文献类型:期刊论文
作者 | Tan SS ; Su AH ; Li WH ; Zhou E |
刊名 | journal of polymer science part b-polymer physics
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出版日期 | 2000 |
卷号 | 38期号:1页码:53-60 |
关键词 | MORPHOLOGICAL-CHANGES ETHER KETONE) POLY(ETHYLENE-TEREPHTHALATE) POLYMERS PEEK |
ISSN号 | 0887-6266 |
通讯作者 | tan ss |
中文摘要 | after isothermal crystallization, poly(ethylene terephthalate) (pet) showed double endothermic behavior in the differential scanning calorimetry (dsc) heating scan. during the heating scans of semicrystalline pet, a metastable melt which comes from melting thinner lamellar crystal populations formed between the low and the upper endothermic temperatures. the metastable melt can recrystallize immediately just above the low melting temperature and form thicker lamellae than the original ones. the thickness and perfection depends on the crystallization time and crystallization temperature. the crystallization kinetics of this metastable melt can be determined by means of dsc. the kinetics analysis showed that the isothermal crystallization of the metastable pet melt proceeds with an avrami exponent of n = 1.0 similar to 1.2, probably reflecting one-dimensional or irregular line growth of the crystal occurring between the existing main lamellae with heterogeneous nucleation. this is in agreement with the hypothesis that the melting peaks are associated with two distinct crystal populations with different thicknesses. (c) 2000 john wiley & sons, inc. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000084143700006 |
公开日期 | 2010-11-04 |
源URL | [http://202.98.16.49/handle/322003/19953] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Tan SS,Su AH,Li WH,et al. New insight into melting and crystallization behavior in semicrystalline poly(ethylene terephthalate)[J]. journal of polymer science part b-polymer physics,2000,38(1):53-60. |
APA | Tan SS,Su AH,Li WH,&Zhou E.(2000).New insight into melting and crystallization behavior in semicrystalline poly(ethylene terephthalate).journal of polymer science part b-polymer physics,38(1),53-60. |
MLA | Tan SS,et al."New insight into melting and crystallization behavior in semicrystalline poly(ethylene terephthalate)".journal of polymer science part b-polymer physics 38.1(2000):53-60. |
入库方式: OAI收割
来源:长春应用化学研究所
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