Gas-phase ion-molecule reactions of C-60 with the plasma of methyl acrylate
文献类型：期刊论文
| 作者 | Liu ZY ; Guo T ; Guo XH ; Liu SY ; Przybylski M ; Ma L |
| 刊名 | european journal of mass spectrometry
 |
| 出版日期 | 2001 |
| 卷号 | 7期号:6页码:461-465 |
| 关键词 | MASS-SPECTROMETRY
|
| ISSN号 | 1469-0667 |
| 通讯作者 | liu sy |
| 中文摘要 | the gas-phase ion-molecule reactions of c-60 with the plasma generated from methyl acrylate under self-chemical ionization conditions were studied by use of a triple-quadrupole mass spectrometer. the adduct cation [c60c3h3o](+) and protonated molecular ion [c60h](+) were observed as the major product ions. the former adduct ion is formed by electrophilic reaction of c-60 with the ion [ch2=chco](+), a main fragment ion resulting from the methyl acrylate molecular ion [ch2=chcooch3](+) through alpha cleavage. the latter ion is generated by proton transfer from protonated methyl acrylate to c-60. semi-empirical quantum chemical calculations have been performed for the eight possible isomers of [c60c3h3o](+) at the hartree-fock level by use of the ami method. the results show three types of cycloadducts as the most stable structures among the possible isomers. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000173694400005 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/20407]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu ZY,Guo T,Guo XH,et al. Gas-phase ion-molecule reactions of C-60 with the plasma of methyl acrylate[J]. european journal of mass spectrometry,2001,7(6):461-465. |
| APA | Liu ZY,Guo T,Guo XH,Liu SY,Przybylski M,&Ma L.(2001).Gas-phase ion-molecule reactions of C-60 with the plasma of methyl acrylate.european journal of mass spectrometry,7(6),461-465. |
| MLA | Liu ZY,et al."Gas-phase ion-molecule reactions of C-60 with the plasma of methyl acrylate".european journal of mass spectrometry 7.6(2001):461-465. |
入库方式： OAI收割
来源：长春应用化学研究所
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