Voltammetric study of the sodium ion transfer across micro-water/1,2-dichloroethane interface facilitated by terminal-vinyl liquid crystal crown ether
文献类型：期刊论文
| 作者 | Tong YH ; Huang ZF ; Shao YH ; Wang EK |
| 刊名 | electroanalysis
 |
| 出版日期 | 2001 |
| 卷号 | 13期号:18页码:1481-1484 |
| 关键词 | IMMISCIBLE ELECTROLYTE-SOLUTIONS MICRO-ITIES WATER NITROBENZENE TIP |
| ISSN号 | 1040-0397 |
| 通讯作者 | shao yh |
| 中文摘要 | sodium ion transfer across micro-water/1,2-dichloroethane (dce) interface facilitated by a novel ionophore, terminal-vinyl liquid crystal crown ether (lcce) was studied by cyclic voltammetry. lcces have potential applications because of their physicochemical properties and the utilization of crown ethers as selective ionophoric units in other functionalized compounds are interesting. host-guest-type behavior for such compounds in the liquid-crystalline state is studied. the experimental results suggest that the transfer of the sodium ion facilitated by lcce was controlled by diffusion of lcce from bulk solution of dce to the interface. the diffusion coefficient of lcce in dce was calculated to be equal to (3.62 +/- 0.20) x 10(-6) cm(2)/s. steady-state voltammograms are due to sodium ion transfer facilitated by the formation of 1: 1 metal (m)-lcce complex at the interface and the mechanism tends to be transfer by interfacial complexation or dissociation (tic or tid). the stability constant of the complex formed was determined to be log beta(o) = 5.5 in dce phase. the influence of parameters such as concentration of sodium ion and concentration of lcce on the sodium ion transfer was investigated. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000173255500003 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/20411]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Tong YH,Huang ZF,Shao YH,et al. Voltammetric study of the sodium ion transfer across micro-water/1,2-dichloroethane interface facilitated by terminal-vinyl liquid crystal crown ether[J]. electroanalysis,2001,13(18):1481-1484. |
| APA | Tong YH,Huang ZF,Shao YH,&Wang EK.(2001).Voltammetric study of the sodium ion transfer across micro-water/1,2-dichloroethane interface facilitated by terminal-vinyl liquid crystal crown ether.electroanalysis,13(18),1481-1484. |
| MLA | Tong YH,et al."Voltammetric study of the sodium ion transfer across micro-water/1,2-dichloroethane interface facilitated by terminal-vinyl liquid crystal crown ether".electroanalysis 13.18(2001):1481-1484. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。