Gas and water vapor transport through a series of novel poly(aryl ether sulfone) membranes
文献类型：期刊论文
| 作者 | Wang ZG ; Chen TL ; Xu JP |
| 刊名 | macromolecules
 |
| 出版日期 | 2001 |
| 卷号 | 34期号:26页码:9015-9022 |
| 关键词 | PERMEATION BEHAVIOR MOLECULAR-STRUCTURE SORPTION SYMMETRY POLYSULFONES PERMEABILITY POLYMERS OXIDE) |
| ISSN号 | 0024-9297 |
| 通讯作者 | wang zg |
| 中文摘要 | the permeation behavior of water vapor, h-2, co2, o-2, n-2, and ch4 gases in a series of novel poly(aryl ether sulfone)s has been examined over a temperature range of 30-100 degreesc. these polymers include four alkyl-substituted cardo poly(aryl ether sulfone)s and four intermolecular interaction enhanced poly(aryl ether sulfone)s. their water vapor and gas transport properties were compared to the unmodified cardo poly(aryl ether sulfone) (pes-c). it was found that the bulky alkyl substituents on the phenylene rings were advantageous for gas permeability, while the intermolecular hydrogen bonds and ionic bonds resulted in a considerable increase in gas permselectivity. the causes of the trend were interpreted according to free volume, interchain distance, and glass transition temperature, together with the respective contribution of gas solubility and diffusivity to the overall permeability. of interest was the observation that impes-l, which simultaneously bears bulky isopropyl substituent and pendant carboxylic groups, displayed 377% higher o-2 permeability and 5.3% higher o-2/n-2 permselectivity than pes-c. furthermore, sodium salt form pes-na+ and potassium salt form pes-k+ exhibited water vapor permeability twice as high as pes-c and h2o/n-2 selectivity in 10(5) order of magnitude. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000172779300031 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/20441]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang ZG,Chen TL,Xu JP. Gas and water vapor transport through a series of novel poly(aryl ether sulfone) membranes[J]. macromolecules,2001,34(26):9015-9022. |
| APA | Wang ZG,Chen TL,&Xu JP.(2001).Gas and water vapor transport through a series of novel poly(aryl ether sulfone) membranes.macromolecules,34(26),9015-9022. |
| MLA | Wang ZG,et al."Gas and water vapor transport through a series of novel poly(aryl ether sulfone) membranes".macromolecules 34.26(2001):9015-9022. |
入库方式： OAI收割
来源：长春应用化学研究所
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