A study of tetraethylammonium ion transfer across a micro liquid/liquid interface
文献类型:期刊论文
作者 | Tong YH ; Shao YH ; Wang EK |
刊名 | chinese journal of analytical chemistry
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出版日期 | 2001 |
卷号 | 29期号:11页码:1241-1245 |
关键词 | LIQUID LIQUID INTERFACE MICROPIPETTE VOLTAMMETRY TIP |
ISSN号 | 0253-3820 |
通讯作者 | shao yh |
中文摘要 | tetraethylammonium (tea(+)) ion transfer across micro-liquid/liquid interface has been studied with cyclic voltammetric measurements. the results showed that voltammetric responses of the currents obtained were peak and steady-state for tea(+) transfer from inside and outside of the micropipette when the radius was bigger than 3 mum. however, the currents were pseudo-steady-state when the micropipette diameters were less than 3 mum. the values of i(p) decreased with decreasing concentration of tea(+). peak current was proportional to the square root of the scan rate and it obeyed a randles-sevcik type relationship. the mechanism of mass transport across a liquid/ liquid microinterface for tea(+) system was aslo discussed. |
收录类别 | SCI收录期刊论文 |
语种 | 中文 |
WOS记录号 | WOS:000172453900001 |
公开日期 | 2010-11-04 |
源URL | [http://202.98.16.49/handle/322003/20465] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Tong YH,Shao YH,Wang EK. A study of tetraethylammonium ion transfer across a micro liquid/liquid interface[J]. chinese journal of analytical chemistry,2001,29(11):1241-1245. |
APA | Tong YH,Shao YH,&Wang EK.(2001).A study of tetraethylammonium ion transfer across a micro liquid/liquid interface.chinese journal of analytical chemistry,29(11),1241-1245. |
MLA | Tong YH,et al."A study of tetraethylammonium ion transfer across a micro liquid/liquid interface".chinese journal of analytical chemistry 29.11(2001):1241-1245. |
入库方式: OAI收割
来源:长春应用化学研究所
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