Investigation of proton transfer across the water/1,2-dichloroethane interface by o-phenanthroline using glass micro/nano-pipets and cyclic voltammetry
文献类型：期刊论文
| 作者 | Yuan Y ; Su B ; Shao YH |
| 刊名 | chemical journal of chinese universities-chinese
 |
| 出版日期 | 2001 |
| 卷号 | 22期号:11页码:1819-1823 |
| 关键词 | IMMISCIBLE ELECTROLYTE-SOLUTIONS ASCENDING WATER ELECTRODE LIQUID-LIQUID INTERFACE ION TRANSFER-REACTIONS METAL EXTRACTANTS NITROBENZENE INTERFACE POTASSIUM-ION 1 COMPLEXES DIBENZO-18-CROWN-6 10-PHENANTHROLINE |
| ISSN号 | 0251-0790 |
| 通讯作者 | shao yh |
| 中文摘要 | facilitated proton transfer across the water/1,2-dichloroethane (dce) interface supported on the tips of micro- and nano-pipets by o-phenanthroline (phen) was studied by using cyclic voltammetry. the formed micro- and nano-liquid/liquid interfaces functioned as micro- and nano-electrodes under certain experimental conditions. the dependence of the half-wave potentials on the aqueous solutions acidities was studied and the ratio of association constants between phen and proton in the aqueous and dce phases was calculated by the method proposed by matsuda et al.. the standard rate constant (k(0)) and the transfer coefficient (alpha) evaluated by using nano-pipets were equal to 0.183 +/- 0.054 cm/s and 0.70 +/- 0.09, respectively. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 中文 |
| WOS记录号 | WOS:000172272100009 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/20477]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yuan Y,Su B,Shao YH. Investigation of proton transfer across the water/1,2-dichloroethane interface by o-phenanthroline using glass micro/nano-pipets and cyclic voltammetry[J]. chemical journal of chinese universities-chinese,2001,22(11):1819-1823. |
| APA | Yuan Y,Su B,&Shao YH.(2001).Investigation of proton transfer across the water/1,2-dichloroethane interface by o-phenanthroline using glass micro/nano-pipets and cyclic voltammetry.chemical journal of chinese universities-chinese,22(11),1819-1823. |
| MLA | Yuan Y,et al."Investigation of proton transfer across the water/1,2-dichloroethane interface by o-phenanthroline using glass micro/nano-pipets and cyclic voltammetry".chemical journal of chinese universities-chinese 22.11(2001):1819-1823. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。