Hydrothermal synthesis and crystal structure of [{Cu(2,2 '-bpy)(2)}(2)Mo8O26]: a beta-octamolybdate cluster covalently bonded to two {Cu(2,2 '-bpy)(2)}(2+) coordination complexes via bridging oxo groups
文献类型：期刊论文
| 作者 | Chen LD ; Wang YH ; Hu CW ; Feng LY ; Wang EB ; Hu NH ; Jia HQ |
| 刊名 | journal of solid state chemistry
 |
| 出版日期 | 2001 |
| 卷号 | 161期号:1页码:173-176 |
| 关键词 | TRANSITION-METAL COMPLEXES INORGANIC HYBRID MATERIALS COMPOSITE-SOLIDS POLYOXOMOLYBDATE CLUSTERS MOLYBDATE FAMILY OXIDE CLUSTERS CHEMISTRY CHAINS MOLYBDENUM NI |
| ISSN号 | 0022-4596 |
| 通讯作者 | hu cw |
| 中文摘要 | an organic-inorganic hybrid solid, (cu(2,2'-bpy)(2))(2)mo8o26, has been hydrothermally synthesized and structurally characterized by single-crystal x-ray diffraction. dark green crystals crystallize in the orthorhombic system, space group pna21, a = 24.164(5), b = 18.281(4), c = 11.877(2) angstrom, alpha = 90 degrees, beta = 90 degrees, gamma = 90 degrees, v= 5247(2) angstrom (3), z = 4, lambda (mok alpha) = 0.71073 angstrom (r(f) = 0.0331 for 5353 reflections). data were collected on a siemens p4 four-circle diffractometer at 293 k in the range 1.69 degrees < theta < 25.04 degrees using the omega -scan technique. the structure was solved by the direct method and refined by full-matrix least squares on f-2 using shelxl-93. the structure of this compound consists of discrete (cu(2,2'-bpy)(2))(2)mo8o26 clusters, constructed from beta -octamolybdate subunits ((mo8o26)(4-)) covalently bonded to two (cu(2,2'-bpy)(2))(2+) coordination complexes via bridging oxo groups that connect two adjacent molybdenum sites. (c) 2001 academic press. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000171804400024 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/20517]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Chen LD,Wang YH,Hu CW,et al. Hydrothermal synthesis and crystal structure of [{Cu(2,2 '-bpy)(2)}(2)Mo8O26]: a beta-octamolybdate cluster covalently bonded to two {Cu(2,2 '-bpy)(2)}(2+) coordination complexes via bridging oxo groups[J]. journal of solid state chemistry,2001,161(1):173-176. |
| APA | Chen LD.,Wang YH.,Hu CW.,Feng LY.,Wang EB.,...&Jia HQ.(2001).Hydrothermal synthesis and crystal structure of [{Cu(2,2 '-bpy)(2)}(2)Mo8O26]: a beta-octamolybdate cluster covalently bonded to two {Cu(2,2 '-bpy)(2)}(2+) coordination complexes via bridging oxo groups.journal of solid state chemistry,161(1),173-176. |
| MLA | Chen LD,et al."Hydrothermal synthesis and crystal structure of [{Cu(2,2 '-bpy)(2)}(2)Mo8O26]: a beta-octamolybdate cluster covalently bonded to two {Cu(2,2 '-bpy)(2)}(2+) coordination complexes via bridging oxo groups".journal of solid state chemistry 161.1(2001):173-176. |
入库方式： OAI收割
来源：长春应用化学研究所
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