Studies of the ortho effect in fragmentations of acetyl ion adducts of disubstituted benzenes
文献类型：期刊论文
| 作者 | Li ZL ; Song FR ; Liu SY |
| 刊名 | rapid communications in mass spectrometry
 |
| 出版日期 | 2001 |
| 卷号 | 15期号:20页码:1893-1898 |
| 关键词 | TRANS-CYCLOPROPANE DERIVATIVES IONIZATION MASS-SPECTRA ORGANIC-MOLECULES HYDROGEN TRANSFER CIS-CYCLOPROPANE ELECTRON-IMPACT GAS-PHASE SPECTROMETRY REARRANGEMENTS DISSOCIATION |
| ISSN号 | 0951-4198 |
| 通讯作者 | li zl |
| 中文摘要 | the ion-molecule reactions of disubstituted benzenes under chemical ionization conditions with acetyl chloride as reagent gas were examined, and the fragmentation reactions of the adduct ions (mostly proton and acetyl ion adducts) were studied by collision-induced dissociation. electron-releasing substituents favored the adduct reactions, and electron-withdrawing groups did not. the position and properties of substituting groups had an effect on the relative abundances of the adduct ions. several examples of the ortho effect were observed. the fragmentation reaction of the adduct ions formed by ortho-benzenediamine with the acetyl ion was similar to the reductive alkylation reaction of amines in the condensed phase. copyright (c) 2001 john wiley & sons, ltd. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000171688300001 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/20535]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li ZL,Song FR,Liu SY. Studies of the ortho effect in fragmentations of acetyl ion adducts of disubstituted benzenes[J]. rapid communications in mass spectrometry,2001,15(20):1893-1898. |
| APA | Li ZL,Song FR,&Liu SY.(2001).Studies of the ortho effect in fragmentations of acetyl ion adducts of disubstituted benzenes.rapid communications in mass spectrometry,15(20),1893-1898. |
| MLA | Li ZL,et al."Studies of the ortho effect in fragmentations of acetyl ion adducts of disubstituted benzenes".rapid communications in mass spectrometry 15.20(2001):1893-1898. |
入库方式： OAI收割
来源：长春应用化学研究所
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