Synthesis and characterization of polynuclear half-sandwich lanthanoid complexes [Na(THF)(6)](2)[(Cp6Sm6Se13)-Sm-t] and [Li(LHF4](2)[Cp6Nd6Se13]
文献类型：期刊论文
| 作者 | Cheng YX ; Jin GX ; Shen Q ; Lin YH |
| 刊名 | journal of organometallic chemistry
 |
| 出版日期 | 2001 |
| 卷号 | 631期号:1-2页码:94-98 |
| 关键词 | PENTAMETHYLCYCLOPENTADIENYL IRIDIUM COMPLEXES CRYSTAL-STRUCTURE CHALCOGENIDO LIGANDS NEODYMIUM COMPLEX SELENIUM SULFUR SE CHEMISTRY ANIONS TE |
| ISSN号 | 0022-328x |
| 通讯作者 | jin gx |
| 中文摘要 | the half-sandwich tert-butyl cyclopentadienyl lanthanoid complexes {[cp ' ln(thf)](2)(mu (2)-cl)(2)(mu (3)-cl)(3)na(thf)}(n) [cp ' = eta (5)-' buc5h4; ln = nd (1a), sm (1b), gd (1c), yb (1d)] are prepared by the reaction of anhydrous lanthanoid trichloride, lncl(3), with nacp ' in thf solution. complex 1b reacts with na2se5 to give hexanuclear samarium polyselenide complexes [na(thf)(6)](2)[cp-6' sm6(mu (6)-se)(mu -se-2)(6)] (2). an analogous cyclopentadienyl neodymium polyselenide complex [li(thf)(4)](2)[cp6nd6(mu (6)-se)(mu -se-2)(6)] (3) is synthesized by the reaction of [cpndcl2. 2licl . 5thf] with na2se5 in thf solution. the molecular structures of 1a and 2 were determined by x-ray crystal structure analysis. complex 2 contains an interstitial selenium atom which is coordinated with six samarium atoms. (c) 2001 elsevier science bn. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000170950900014 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/20575]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Cheng YX,Jin GX,Shen Q,et al. Synthesis and characterization of polynuclear half-sandwich lanthanoid complexes [Na(THF)(6)](2)[(Cp6Sm6Se13)-Sm-t] and [Li(LHF4](2)[Cp6Nd6Se13][J]. journal of organometallic chemistry,2001,631(1-2):94-98. |
| APA | Cheng YX,Jin GX,Shen Q,&Lin YH.(2001).Synthesis and characterization of polynuclear half-sandwich lanthanoid complexes [Na(THF)(6)](2)[(Cp6Sm6Se13)-Sm-t] and [Li(LHF4](2)[Cp6Nd6Se13].journal of organometallic chemistry,631(1-2),94-98. |
| MLA | Cheng YX,et al."Synthesis and characterization of polynuclear half-sandwich lanthanoid complexes [Na(THF)(6)](2)[(Cp6Sm6Se13)-Sm-t] and [Li(LHF4](2)[Cp6Nd6Se13]".journal of organometallic chemistry 631.1-2(2001):94-98. |
入库方式： OAI收割
来源：长春应用化学研究所
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