Electrochemistry and electrochemiluminescence of stable tris(2,2 '-bipyridyl)ruthenium(II) monolayer assembled on benzene sulfonic acid modified glassy carbon electrode
文献类型：期刊论文
| 作者 | Wang HY ; Xu GB ; Dong SJ |
| 刊名 | talanta
 |
| 出版日期 | 2001 |
| 卷号 | 55期号:1页码:61-67 |
| 关键词 | ELECTROGENERATED CHEMILUMINESCENCE COVALENT MODIFICATION CHEMI-LUMINESCENCE DIAZONIUM SALTS REDUCTION EMISSION NAFION GOLD SURFACTANT REAGENT |
| ISSN号 | 0039-9140 |
| 通讯作者 | wang hy |
| 中文摘要 | an electrochemically stable monolayer of tris(2,2'-bipyridyl)ruthenium(ii) was obtained for the first time. it was based on the electrostatic attachment of ru(bpy)(3)(2+) to the benzene sulfonic acid monolayer film, which was covalently bound onto glassy carbon electrode by the electrochemical reduction of diazobenzene sulfonic acid. the surface-confined ru(bpy)(3)(2+) underwent reversible surface process, and reacted with the coreactant, tripropylamine, to produce electrochemiluminescence. in view of the stability of the electrode, the results strongly suggested that light was emitted from the surface-confined ru(bpy)(3)(2+), not from the detached ru(bpy)(3)(2+). the ru(bpy)(3)(2+) modified electrode was used to the determination of tripropylamine. it showed good linearity in the concentration range from 5 mum to 1 mum with a detection limit of 1 mum (s/n = 4). the good stability of the ru(bpy)(3)(2+) modified electrode also showed that the benzene sulfonic acid monolayer film prepared can be served as an excellent support to construct multilayers. (c) 2001 elsevier science b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000170722600006 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/20597]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang HY,Xu GB,Dong SJ. Electrochemistry and electrochemiluminescence of stable tris(2,2 '-bipyridyl)ruthenium(II) monolayer assembled on benzene sulfonic acid modified glassy carbon electrode[J]. talanta,2001,55(1):61-67. |
| APA | Wang HY,Xu GB,&Dong SJ.(2001).Electrochemistry and electrochemiluminescence of stable tris(2,2 '-bipyridyl)ruthenium(II) monolayer assembled on benzene sulfonic acid modified glassy carbon electrode.talanta,55(1),61-67. |
| MLA | Wang HY,et al."Electrochemistry and electrochemiluminescence of stable tris(2,2 '-bipyridyl)ruthenium(II) monolayer assembled on benzene sulfonic acid modified glassy carbon electrode".talanta 55.1(2001):61-67. |
入库方式： OAI收割
来源：长春应用化学研究所
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