中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Study of the mechanism for controlled crystallization of BaF2 under two kinds of monolayers

文献类型:期刊论文

作者Lu L ; Cui H ; Li W ; Zhang H ; Xi S
刊名journal of materials research
出版日期2001
卷号16期号:8页码:2415-2420
关键词LANGMUIR-BLODGETT-FILMS ARACHIDIC ACID MONOLAYERS CALCIUM-PHOSPHATE WATER INTERFACES CRYSTALS GROWTH RECOGNITION NUCLEATION
ISSN号0884-2914
通讯作者xi s
中文摘要controlled crystallization of baf2 under two different kinds of monolayers, octadecylamine [ch3(ch2)(17)nh2] and hexadecanol [ch3(ch2)(14)ch2oh], has been studied by using x-ray diffraction (xrd) and scanning electron microscope. it was found that the monolayer headgroup, the degree of ionization of the headgroup, etc., had a complicated effect on the selectivity of monolayers for crystal and on the morphology and orientation of crystals grown under the compressed monolayers. at ph = 7.0, xrd analysis showed that (100)-oriented baf2 crystals were formed under the octadecylamine monolayer, while several kinds of crystals were found under the hexadecanol monolayer. in comparison, at ph = 8.5, both (100)-oriented baf2 and (111)-oriented ba(no3)(2) crystals were obtained under the monolayer of octadecylamine. however, crystals formed under hexadecanol monolayer consist of baf2, ba(no3)(2), etc. the detailed mechanism for crystallization was discussed in terms of the specific interaction and lattice matching between the monolayer headgroup and the nucleating species.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000170227500037
公开日期2010-11-04
源URL[http://202.98.16.49/handle/322003/20663]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Lu L,Cui H,Li W,et al. Study of the mechanism for controlled crystallization of BaF2 under two kinds of monolayers[J]. journal of materials research,2001,16(8):2415-2420.
APA Lu L,Cui H,Li W,Zhang H,&Xi S.(2001).Study of the mechanism for controlled crystallization of BaF2 under two kinds of monolayers.journal of materials research,16(8),2415-2420.
MLA Lu L,et al."Study of the mechanism for controlled crystallization of BaF2 under two kinds of monolayers".journal of materials research 16.8(2001):2415-2420.

入库方式: OAI收割

来源:长春应用化学研究所

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