中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and crystal structure of a novel compound constructed from tris-(2, 2 '-bipy)ruthenium(II) and decatungstate

文献类型:期刊论文

作者Han ZB ; Wang EB ; Luan GY ; Li YG ; Hu CW ; Wang P ; Hu NH ; Jia HQ
刊名inorganic chemistry communications
出版日期2001
卷号4期号:8页码:427-429
关键词ENERGY-TRANSFER SALT TRIS(2 COMPLEX 2'-BIPYRIDINE)RUTHENIUM(II)
ISSN号1387-7003
通讯作者wang eb
中文摘要self-assembly of tris-[2,2 ' -bipyridine]ruthenium(ii) chloride with decatunstate produced a novel cation radical salt, [ru(bpy)(3)](2)[w10o32] . 3dmso. this is the first product of 2,2 ' -bipyridineruthenium(ii)-polyoxometalates species. crystal data: monoclinic, p2(1)/c, a = 12.902(3) angstrom, b = 21.487(3) angstrom, c = 15.854(5) angstrom, beta = 93.46(2)degrees, v = 4387(2) angstrom (3), z = 2, r-1 = 0.0599, wr2 = 0.1183. x-ray crystallographic study showed that the crystal structure was constructed by electyrostatic attraction and c-h . . .o hydrogen bonds between tris-[2,2 ' -bipyridine]ruthenium(ii) and decatungstate polyanion. the tris-[2,2 ' -bipyridine]ruthenium molecules occupy cavities in the polyoxometalate lattice ordered along b-axis. (c) 2001 elsevier science b.v. all rights reserved.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000170014400015
公开日期2010-11-04
源URL[http://202.98.16.49/handle/322003/20677]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Han ZB,Wang EB,Luan GY,et al. Synthesis and crystal structure of a novel compound constructed from tris-(2, 2 '-bipy)ruthenium(II) and decatungstate[J]. inorganic chemistry communications,2001,4(8):427-429.
APA Han ZB.,Wang EB.,Luan GY.,Li YG.,Hu CW.,...&Jia HQ.(2001).Synthesis and crystal structure of a novel compound constructed from tris-(2, 2 '-bipy)ruthenium(II) and decatungstate.inorganic chemistry communications,4(8),427-429.
MLA Han ZB,et al."Synthesis and crystal structure of a novel compound constructed from tris-(2, 2 '-bipy)ruthenium(II) and decatungstate".inorganic chemistry communications 4.8(2001):427-429.

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来源:长春应用化学研究所

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