Synthesis and crystal structure of [Nd(eta(6)-1,3,5-C6H3Me3)(AlCl4)(3)]( C6H6) and structural comparison of Ln(eta(6)-arene)(AlCl4)(3)
文献类型：期刊论文
| 作者 | Yao YM ; Zhang Y ; Shen Q ; Liu QC ; Meng QJ ; Lin YH |
| 刊名 | chinese journal of chemistry
 |
| 出版日期 | 2001 |
| 卷号 | 19期号:6页码:588-592 |
| 关键词 | TETRACHLORIDES) COMPLEX SM |
| ISSN号 | 1001-604x |
| 通讯作者 | shen q |
| 中文摘要 | reaction of ndcl3, with alcl3 and mesitylene in benzene gives complex [nd(eta (6)-1,3,5-c6h3me3) (alcl4)(3)] (c6h6) (1) which was characterized by elemental analysis, ir spectra, ms and x-lay diffractions. the x-ray determination indicates that 1 has a distorted pentagonal bipyramidal geometry and crystallizes in the monoclinic, space group p2(1)/n with a = 0.9586(2), b = 1.1717(5), c = 2.8966(7) nm, beta = 90.85 (2)degrees, v = 3.2529(6) nm(3), d-c = 1.573 g/cm(3), z = 4. a comparison of bond parameters for all the reported ln(eta (6)-ar) (alcl4)(3) complexes indicates that the bond distance of ln-c is shortened with the increasing of methyl group on benzene and with the decreasing of radius of lanthanide ions. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000169449100008 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/20713]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yao YM,Zhang Y,Shen Q,et al. Synthesis and crystal structure of [Nd(eta(6)-1,3,5-C6H3Me3)(AlCl4)(3)]( C6H6) and structural comparison of Ln(eta(6)-arene)(AlCl4)(3)[J]. chinese journal of chemistry,2001,19(6):588-592. |
| APA | Yao YM,Zhang Y,Shen Q,Liu QC,Meng QJ,&Lin YH.(2001).Synthesis and crystal structure of [Nd(eta(6)-1,3,5-C6H3Me3)(AlCl4)(3)]( C6H6) and structural comparison of Ln(eta(6)-arene)(AlCl4)(3).chinese journal of chemistry,19(6),588-592. |
| MLA | Yao YM,et al."Synthesis and crystal structure of [Nd(eta(6)-1,3,5-C6H3Me3)(AlCl4)(3)]( C6H6) and structural comparison of Ln(eta(6)-arene)(AlCl4)(3)".chinese journal of chemistry 19.6(2001):588-592. |
入库方式： OAI收割
来源：长春应用化学研究所
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