The photo-induced decarbonylation of Cp ' M(NO)(CO)(2) (M = Cr, Mo, W) with diorgano dichalcogenides (R2E2; E = S, Se; R = Me, Ph)
文献类型:期刊论文
作者 | Jin GX ; Herberhold M |
刊名 | transition metal chemistry
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出版日期 | 2001 |
卷号 | 26期号:4-5页码:445-447 |
关键词 | COMPLEXES LIGANDS |
ISSN号 | 0340-4285 |
通讯作者 | jin gx |
中文摘要 | the photo-induced decarbonylation of cp'cr(no)(co)(2) (1a) in mecn solution in the presence of r2e2 (e = s, se; r = me, ph) leads to the formation of chalcogenolato-bridged binuclear complexes cp-2'cr-2(no)(2)(mu -er)(2) [e = s; r = me (2a), ph (3a); e = se, r = me (4a), ph (5a)] while reactions between cp'm(no)(co)(2) [m = mo (1b), w (1c)] and ph2e2 (e = s, se) result in mononuclear complexes cp'm(no)(eph)(2) [m = mo; e = s (9b), se (10b); m = w, e = s (11c), se (12c)]. the corresponding reactions of (1b) with me2e2 (e = s, se) yielded both mono and binuclear complexes: cp'mo(no)(seme)(2) (8b), cp-2'mo-2(no)(2)(mu -eme)(2) [e = s (6b), se (7b)]. the new complexes have been characterized by i.r., h-1-, c-13-n.m.r. spectra and by electron-impact mass spectrometry. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000169221600015 |
公开日期 | 2010-11-04 |
源URL | [http://202.98.16.49/handle/322003/20727] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Jin GX,Herberhold M. The photo-induced decarbonylation of Cp ' M(NO)(CO)(2) (M = Cr, Mo, W) with diorgano dichalcogenides (R2E2; E = S, Se; R = Me, Ph)[J]. transition metal chemistry,2001,26(4-5):445-447. |
APA | Jin GX,&Herberhold M.(2001).The photo-induced decarbonylation of Cp ' M(NO)(CO)(2) (M = Cr, Mo, W) with diorgano dichalcogenides (R2E2; E = S, Se; R = Me, Ph).transition metal chemistry,26(4-5),445-447. |
MLA | Jin GX,et al."The photo-induced decarbonylation of Cp ' M(NO)(CO)(2) (M = Cr, Mo, W) with diorgano dichalcogenides (R2E2; E = S, Se; R = Me, Ph)".transition metal chemistry 26.4-5(2001):445-447. |
入库方式: OAI收割
来源:长春应用化学研究所
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