Half-sandwich metal diselenolate complexes Cp#M(NO)(SePh)(2) (M = Mo or W; Cp# = Cp or MeCp) as ligands. Synthesis of selenolate-bridged heterobimetallic compounds
文献类型：期刊论文
| 作者 | Jin GX ; Herberhold M |
| 刊名 | transition metal chemistry
 |
| 出版日期 | 2001 |
| 卷号 | 26期号:4-5页码:496-499 |
| 关键词 | MOLECULAR-STRUCTURE CRYSTAL-STRUCTURE ELECTROCHEMISTRY REACTIVITY MECHANISM |
| ISSN号 | 0340-4285 |
| 通讯作者 | jin gx |
| 中文摘要 | the reactions of half-sandwich diselenolate mo and w complexes (cpm)-m-#(no)(seph)(2) (m = mo; cp-# = cp' (1a), mecp (1b); m = w; cp-# = cp' (1c)) with (norb)mo(co)(4), ni(cod)(2) and fe(co)(5) have been investigated. treatment of (1a), (1b) and (1c) with (norb)mo(co)(4) in phme gave the bimetallic complexes: cp'mo(no)(mu -seph)(2)mo(co)(4) (2a), mecpmo(no)(mu -seph)(2)mo(co)(4) (2b) and cp'w(no)(mu -seph)(2)mo(co)(4) (2c) in moderate yields. irradiation of (1a) and (1c) in the presence of fe(co)(5) gave heterobimetallic complexes cp'mo(co)(mu -seph)(2)fe(co)(3) (3a) and cp'w(no)(mu -seph)(2)fe(co)(3) (3c). ni(cod)(2) reacts with two equivalents of (1a), (1b) and (1c) to give [cp'mo(no)(mu -seph)(2)](2)ni (4a), [mecpmo(no)(mu -seph)(2)](2)ni (4b) and [cp'w(no)(mu -seph)(2)](2)ni (4c) in good yields. the new heterobimetallic complexes were characterized by i.r., h-1-n.m.r., c-13-n.m.r. and ei-ms spectroscopy. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000169221600025 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/20729]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Jin GX,Herberhold M. Half-sandwich metal diselenolate complexes Cp#M(NO)(SePh)(2) (M = Mo or W; Cp# = Cp or MeCp) as ligands. Synthesis of selenolate-bridged heterobimetallic compounds[J]. transition metal chemistry,2001,26(4-5):496-499. |
| APA | Jin GX,&Herberhold M.(2001).Half-sandwich metal diselenolate complexes Cp#M(NO)(SePh)(2) (M = Mo or W; Cp# = Cp or MeCp) as ligands. Synthesis of selenolate-bridged heterobimetallic compounds.transition metal chemistry,26(4-5),496-499. |
| MLA | Jin GX,et al."Half-sandwich metal diselenolate complexes Cp#M(NO)(SePh)(2) (M = Mo or W; Cp# = Cp or MeCp) as ligands. Synthesis of selenolate-bridged heterobimetallic compounds".transition metal chemistry 26.4-5(2001):496-499. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。