Electrochemical and in situ spectroelectrochemical behavior of 2,3,7,8,12,13,17,18-octakis(hexyl-thio) tetraazaporphyrin (H(2)OHTTAP) and (Zn(II)OHTTAP)
文献类型：期刊论文
| 作者 | Zhou YX ; Wang ZX ; Wang DK ; Sugiura K ; Sakata Y |
| 刊名 | journal of porphyrins and phthalocyanines
 |
| 出版日期 | 2001 |
| 卷号 | 5期号:6页码:523-527 |
| 关键词 | METALLOPORPHYRINS EPOXIDATION CATALYSTS ALKENES |
| ISSN号 | 1088-4246 |
| 通讯作者 | zhou yx |
| 中文摘要 | the characterization of free base porphyrin 2,3,7,8,12,13,17,18-octakis(hexyl-thio) tetraazaporphyrin (h(2)ohttap) and its zinc(ii) complexes [zn(ii)ohttap] containing eight thioether groups at the beta -pyrrole positions of the macrocycle was reported. results obtained by cyclic voltammetry and differential pulse voltammetry indicated a five-electron reduction in five steps for each complex. they were oxidized in two single-electron-transfer steps to yield pi -cation radicals and dications and reduced in three single-electron-transfer steps to yield pi -anion radicals, dianions and trianions, respectively. the redox property of h(2)ohttap was unusual as compared to porphyrins (pps) and phthalocyanines (pcs). each process was monitored by in situ thin-layer spectroelectrochemistry, which indicated that only the ligand was electroactive. the existence of the eight hexylthio groups was responsible for the intrastack interactions and enhanced intracolumnar and intercolumnar electron motions, resulting in improved conductivity. copyright (c) 2001 john wiley & sons, ltd. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000168945100006 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/20763]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhou YX,Wang ZX,Wang DK,et al. Electrochemical and in situ spectroelectrochemical behavior of 2,3,7,8,12,13,17,18-octakis(hexyl-thio) tetraazaporphyrin (H(2)OHTTAP) and (Zn(II)OHTTAP)[J]. journal of porphyrins and phthalocyanines,2001,5(6):523-527. |
| APA | Zhou YX,Wang ZX,Wang DK,Sugiura K,&Sakata Y.(2001).Electrochemical and in situ spectroelectrochemical behavior of 2,3,7,8,12,13,17,18-octakis(hexyl-thio) tetraazaporphyrin (H(2)OHTTAP) and (Zn(II)OHTTAP).journal of porphyrins and phthalocyanines,5(6),523-527. |
| MLA | Zhou YX,et al."Electrochemical and in situ spectroelectrochemical behavior of 2,3,7,8,12,13,17,18-octakis(hexyl-thio) tetraazaporphyrin (H(2)OHTTAP) and (Zn(II)OHTTAP)".journal of porphyrins and phthalocyanines 5.6(2001):523-527. |
入库方式： OAI收割
来源：长春应用化学研究所
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