NMR and UV-Vis study on phenyl-capped oligoaniline salts
文献类型：期刊论文
| 作者 | Sun ZC ; Jing XB ; Wang XH ; Li J ; Wang FS |
| 刊名 | synthetic metals
 |
| 出版日期 | 2001 |
| 卷号 | 119期号:1-3页码:313-314 |
| ISSN号 | 0379-6779 |
| 通讯作者 | jing xb |
| 中文摘要 | phenyl-capped oligoanilines in the oxidized state and their salts (by camphor sulfonic acid, csa) were comparatively studied by uv-vis and nmr spectroscopy. the uv-vis spectra revealed a similar electron transfer behaviour and similar structure in the tetraaniline to those in polyaniline. upon formation of the salt, h-1 nmr ch peaks of the oligomers showed large shifts to lower fields. the longer the molecule of a oligomer is, the more the shift, indicating that the charge brought into the n atoms by the proton was redistributed over the whole molecule. the ch and quaternary carbon peak-shifts support the electron cloud motion route h -->c -->c -->n -->h. this is in agreement with the four ring bq derivatives model. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000168741500140 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/20787]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Sun ZC,Jing XB,Wang XH,et al. NMR and UV-Vis study on phenyl-capped oligoaniline salts[J]. synthetic metals,2001,119(1-3):313-314. |
| APA | Sun ZC,Jing XB,Wang XH,Li J,&Wang FS.(2001).NMR and UV-Vis study on phenyl-capped oligoaniline salts.synthetic metals,119(1-3),313-314. |
| MLA | Sun ZC,et al."NMR and UV-Vis study on phenyl-capped oligoaniline salts".synthetic metals 119.1-3(2001):313-314. |
入库方式： OAI收割
来源：长春应用化学研究所
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