Fabrication of agar-gel microelectrodes and their application in the study of ion transfer across the agar-water 1,2-dichloroethane interface
文献类型：期刊论文
| 作者 | Tong YH ; Sun P ; Zhang ZQ ; Shao YH |
| 刊名 | journal of electroanalytical chemistry
 |
| 出版日期 | 2001 |
| 卷号 | 504期号:1页码:52-58 |
| 关键词 | IMMISCIBLE ELECTROLYTE-SOLUTIONS LIQUID-LIQUID INTERFACE NITROBENZENE INTERFACE POTASSIUM-ION MICRO-ITIES VOLTAMMETRY DETECTOR DIBENZO-18-CROWN-6 MICROPIPETTE KINETICS |
| ISSN号 | 0022-0728 |
| 通讯作者 | shao yh |
| 中文摘要 | in this paper, we describe a simple procedure to make agar-gel microelectrodes by filling micropipettes. these microelectrodes were used to study k+ transfer across the agar-water \ 1,2-dichloroethane interface facilitated by dibenzo-18-crown-6 (db18c6), and the transfer of tetraethylammonium (tea(+)). the results observed were similar to those obtained at micro-liquid \ liquid interfaces. the effect of various amounts of agar in the aqueous phase was optimized and 3% agar was chosen based on the potential window and solidification time. the different shapes of micro-agar-gel electrodes were prepared in a similar way. the fabricated agar-gel microelectrodes obey the classical micro-disk steady-state current equation, which is different from the behavior of a normal micropipette filled with aqueous solution without silanization. (c) 2001 elsevier science b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000168710800004 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/20803]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Tong YH,Sun P,Zhang ZQ,et al. Fabrication of agar-gel microelectrodes and their application in the study of ion transfer across the agar-water 1,2-dichloroethane interface[J]. journal of electroanalytical chemistry,2001,504(1):52-58. |
| APA | Tong YH,Sun P,Zhang ZQ,&Shao YH.(2001).Fabrication of agar-gel microelectrodes and their application in the study of ion transfer across the agar-water 1,2-dichloroethane interface.journal of electroanalytical chemistry,504(1),52-58. |
| MLA | Tong YH,et al."Fabrication of agar-gel microelectrodes and their application in the study of ion transfer across the agar-water 1,2-dichloroethane interface".journal of electroanalytical chemistry 504.1(2001):52-58. |
入库方式： OAI收割
来源：长春应用化学研究所
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