Synthesis and structure of a novel mononuclear tungsten (VI) citrato complex, (NH4)(3)[Li(H2O)(3)WO3(C6H4O7)]
文献类型：期刊论文
| 作者 | Xu JQ ; Li DM ; Xing YH ; Wang RZ ; Liu SQ ; Wang TG ; Xing Y ; Lin YH ; Jia HQ |
| 刊名 | journal of coordination chemistry
 |
| 出版日期 | 2001 |
| 卷号 | 53期号:1页码:25-33 |
| 关键词 | SINGLE-CRYSTAL STRUCTURE CITRIC-ACID AMMONIUM LIGAND |
| ISSN号 | 0095-8972 |
| 通讯作者 | xu jq |
| 中文摘要 | the first mononuclear tungsten-citrato complex, (nh4)(3)[li(h2o)(3)wo3(c6h4o7)] (1) has been prepared by the reaction of ammonium tetrathio tungstate and lithium citrate in ch3oh - h2o solution at ph 8.2. there are two crystallographically independent anions in the asymmetric crystallographic unit. the crystal structure of the title compound (triclinic, space group p (1) over bar, a = 6.901(1), b = 15.136(3), c = 16.107(3) angstrom, alpha = 75.85(3), beta = 89.89(3), gamma = 89.97(3), v = 1631.4(6) angstrom (3), r = 0.068, r-w = 0.1674 for 3878 reflections with i > 2 sigma (1)), reveals that in the compound a tungsten atom is coordinated to a fully deprotonated citrate as a tridentate ligand and three terminal oxygen atoms to form a distorted coordination octahedron. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000168257100004 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/20829]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Xu JQ,Li DM,Xing YH,et al. Synthesis and structure of a novel mononuclear tungsten (VI) citrato complex, (NH4)(3)[Li(H2O)(3)WO3(C6H4O7)][J]. journal of coordination chemistry,2001,53(1):25-33. |
| APA | Xu JQ.,Li DM.,Xing YH.,Wang RZ.,Liu SQ.,...&Jia HQ.(2001).Synthesis and structure of a novel mononuclear tungsten (VI) citrato complex, (NH4)(3)[Li(H2O)(3)WO3(C6H4O7)].journal of coordination chemistry,53(1),25-33. |
| MLA | Xu JQ,et al."Synthesis and structure of a novel mononuclear tungsten (VI) citrato complex, (NH4)(3)[Li(H2O)(3)WO3(C6H4O7)]".journal of coordination chemistry 53.1(2001):25-33. |
入库方式： OAI收割
来源：长春应用化学研究所
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