中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
In-situ FTIR study on adsorption and oxidation of native and thermally denatured calf thymus DNA at glassy carbon electrodes

文献类型:期刊论文

作者Wang ZX ; Liu DJ ; Dong SJ
刊名biophysical chemistry
出版日期2001
卷号89期号:1页码:87-94
关键词ELECTROCHEMICAL-BEHAVIOR STRIPPING POTENTIOMETRY GRAPHITE ELECTRODE PASTE ELECTRODES NUCLEIC-ACIDS VOLTAMMETRY BINDING
ISSN号0301-4622
通讯作者dong sj
中文摘要in-situ fourier transform infra-red (ftir) spectra of native and thermally denatured calf thymus dna (ct dna) adsorbed and/or oxidized at a glassy carbon (gc) electrode surface are reported. the adsorption of native dna occurs throughout the potential range (-0.2 similar to 1.3 v) studied, and the adsorbing state of dna at electrode surface is changed from through the c=o band of bases and pyrimidine rings to through the c=o of cytosine and imidazole rings while the potential shifts negatively from 1.3 v to -0.2 v. an in-situ ftir spectrum of native ct dna adsorbed at gc electrode surface is similar to that of the dissolved dna, indicating that the structure of ct dna is not distorted while it is adsorbed at the gc electrode surface. in the potential range of -0.2 similar to 1.30 v, the temperature-denatured ct dna is adsorbed at the electrode surface first, then undergoes electrochemical oxidation reaction and following that, diffuses away from the electrode surface. (c) 2001 elsevier science b.v. all rights reserved.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000166721200008
公开日期2010-11-04
源URL[http://202.98.16.49/handle/322003/20973]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Wang ZX,Liu DJ,Dong SJ. In-situ FTIR study on adsorption and oxidation of native and thermally denatured calf thymus DNA at glassy carbon electrodes[J]. biophysical chemistry,2001,89(1):87-94.
APA Wang ZX,Liu DJ,&Dong SJ.(2001).In-situ FTIR study on adsorption and oxidation of native and thermally denatured calf thymus DNA at glassy carbon electrodes.biophysical chemistry,89(1),87-94.
MLA Wang ZX,et al."In-situ FTIR study on adsorption and oxidation of native and thermally denatured calf thymus DNA at glassy carbon electrodes".biophysical chemistry 89.1(2001):87-94.

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来源:长春应用化学研究所

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