In-situ FTIR study on adsorption and oxidation of native and thermally denatured calf thymus DNA at glassy carbon electrodes
文献类型:期刊论文
作者 | Wang ZX ; Liu DJ ; Dong SJ |
刊名 | biophysical chemistry
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出版日期 | 2001 |
卷号 | 89期号:1页码:87-94 |
关键词 | ELECTROCHEMICAL-BEHAVIOR STRIPPING POTENTIOMETRY GRAPHITE ELECTRODE PASTE ELECTRODES NUCLEIC-ACIDS VOLTAMMETRY BINDING |
ISSN号 | 0301-4622 |
通讯作者 | dong sj |
中文摘要 | in-situ fourier transform infra-red (ftir) spectra of native and thermally denatured calf thymus dna (ct dna) adsorbed and/or oxidized at a glassy carbon (gc) electrode surface are reported. the adsorption of native dna occurs throughout the potential range (-0.2 similar to 1.3 v) studied, and the adsorbing state of dna at electrode surface is changed from through the c=o band of bases and pyrimidine rings to through the c=o of cytosine and imidazole rings while the potential shifts negatively from 1.3 v to -0.2 v. an in-situ ftir spectrum of native ct dna adsorbed at gc electrode surface is similar to that of the dissolved dna, indicating that the structure of ct dna is not distorted while it is adsorbed at the gc electrode surface. in the potential range of -0.2 similar to 1.30 v, the temperature-denatured ct dna is adsorbed at the electrode surface first, then undergoes electrochemical oxidation reaction and following that, diffuses away from the electrode surface. (c) 2001 elsevier science b.v. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000166721200008 |
公开日期 | 2010-11-04 |
源URL | [http://202.98.16.49/handle/322003/20973] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Wang ZX,Liu DJ,Dong SJ. In-situ FTIR study on adsorption and oxidation of native and thermally denatured calf thymus DNA at glassy carbon electrodes[J]. biophysical chemistry,2001,89(1):87-94. |
APA | Wang ZX,Liu DJ,&Dong SJ.(2001).In-situ FTIR study on adsorption and oxidation of native and thermally denatured calf thymus DNA at glassy carbon electrodes.biophysical chemistry,89(1),87-94. |
MLA | Wang ZX,et al."In-situ FTIR study on adsorption and oxidation of native and thermally denatured calf thymus DNA at glassy carbon electrodes".biophysical chemistry 89.1(2001):87-94. |
入库方式: OAI收割
来源:长春应用化学研究所
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