Investigation on moleculare and crystal structures of metal complexes with aminopolycarboxylic acids (VII) - Syntheses and structure determination of Na-3[Hg (I) (edta) C1] center dot 6H(2)O
文献类型：期刊论文
| 作者 | Wang J ; Gao JQ ; Zhang XD ; Xing Y ; Jia HQ ; Bai SY ; Lin YH |
| 刊名 | chinese journal of inorganic chemistry
 |
| 出版日期 | 1999 |
| 卷号 | 15期号:1页码:135-138 |
| ISSN号 | 1001-4861 |
| 关键词 | ETHYLENEDIAMINE-N IONS N N' N'-TETRAACETATE |
| 通讯作者 | wang j |
| 中文摘要 | in this paper we describe the moleculare and crystal structures of the na-3[hg( ii )(edta)cl] . 6h(2)o (edta=ethylenediamine-n,n,n',n'-tetraacetate). the crystal data are as follows: orthorhombic, a=8. 083 (2) angstrom , b=13. 870(3) angstrom , c=38. 617(5) angstrom , v=4329. 4 (13) angstrom(3) , z=8, dc= 1. 798 g . cm(-3), mu=5. 564 mm(-1), p(000)=2280, r=0. 0317 and r-w=0. 0731 for 3883 unique reflections. in complex, the complex anion [hg ( ii ) (edta)cl](3-) has a seven-coordination structure like a mono-capped trigonal-prism (c-2v-mtp) in which the edta(4-) acts as a hexadentate ligand with four o atoms and two n atoms and a cl- caps a quadrilateral face as a seventh ligand. it can be known that the hg2+ which has a d(10) electronic structure can form a high-coordinate compound with a hexadentate ligand (edta) because it has a big ionic radius. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 中文 |
| WOS记录号 | WOS:000084247300026 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/21475]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang J,Gao JQ,Zhang XD,et al. Investigation on moleculare and crystal structures of metal complexes with aminopolycarboxylic acids (VII) - Syntheses and structure determination of Na-3[Hg (I) (edta) C1] center dot 6H(2)O[J]. chinese journal of inorganic chemistry,1999,15(1):135-138. |
| APA | Wang J.,Gao JQ.,Zhang XD.,Xing Y.,Jia HQ.,...&Lin YH.(1999).Investigation on moleculare and crystal structures of metal complexes with aminopolycarboxylic acids (VII) - Syntheses and structure determination of Na-3[Hg (I) (edta) C1] center dot 6H(2)O.chinese journal of inorganic chemistry,15(1),135-138. |
| MLA | Wang J,et al."Investigation on moleculare and crystal structures of metal complexes with aminopolycarboxylic acids (VII) - Syntheses and structure determination of Na-3[Hg (I) (edta) C1] center dot 6H(2)O".chinese journal of inorganic chemistry 15.1(1999):135-138. |
入库方式： OAI收割
来源：长春应用化学研究所
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