Synthesis of monodisperse pheyl-capped oligoaniline pentamer and hexamer in the leucoemeraldine oxidation state and EB state and its UV studies
文献类型：期刊论文
| 作者 | Gao JB ; Li K ; Sun H ; Yu YH ; Wang C ; Wu JW ; Zhang WJ ; Ji YP |
| 刊名 | chemical journal of chinese universities-chinese
 |
| 出版日期 | 1999 |
| 卷号 | 20期号:12页码:1960-1964 |
| 关键词 | FUNCTIONALIZED OLIGOANILINES POLYANILINE |
| ISSN号 | 0251-0790 |
| 通讯作者 | zhang wj |
| 中文摘要 | aniline pentamer and hexamer in the leucoemeraldine oxidation state were synthesized through a novel method. the method was accomplished by the reaction of parent aniline tetramer in the pernigraniline oxidation state with diphenylamine and n-phenyl-1,4-phenylenediamine in the leucoemeraldine oxidation state respectively. the oligomers in the leucoemeraldine oxidation state were characterized by ir, nmr, elemental analysis and maldi-ms. aniline pentamer and hexamer in the emeraldine oxidation state were synthesized by the oxidation of ag2o in dmf. it was found that some fragmentation occurred when the pentamer and hexamer were oxidized by (nh4)(2)s2o8 and fecl3. 6h(2)o. the pentamer and hexamer in the emeraldine oxidation state was studied by uv/vis spectra. the relative intensity of exciton peak for pentaaniline showed a little increase compared with that of hexaaniline. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 中文 |
| WOS记录号 | WOS:000084320500032 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/21489]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Gao JB,Li K,Sun H,et al. Synthesis of monodisperse pheyl-capped oligoaniline pentamer and hexamer in the leucoemeraldine oxidation state and EB state and its UV studies[J]. chemical journal of chinese universities-chinese,1999,20(12):1960-1964. |
| APA | Gao JB.,Li K.,Sun H.,Yu YH.,Wang C.,...&Ji YP.(1999).Synthesis of monodisperse pheyl-capped oligoaniline pentamer and hexamer in the leucoemeraldine oxidation state and EB state and its UV studies.chemical journal of chinese universities-chinese,20(12),1960-1964. |
| MLA | Gao JB,et al."Synthesis of monodisperse pheyl-capped oligoaniline pentamer and hexamer in the leucoemeraldine oxidation state and EB state and its UV studies".chemical journal of chinese universities-chinese 20.12(1999):1960-1964. |
入库方式： OAI收割
来源：长春应用化学研究所
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