Gas-phase ion - Molecule reactions of neutral C-60 with the plasmas of alkyl methyl ethers and primary alcohols
文献类型：期刊论文
| 作者 | Ma L ; Liu ZY ; Wang WJ ; Guo XH ; Liu SY |
| 刊名 | journal of physical chemistry a
 |
| 出版日期 | 1999 |
| 卷号 | 103期号:43页码:8634-8639 |
| 关键词 | FULLERENE CATIONS ADDUCT CATIONS CHARGE-STATE BUCKMINSTERFULLERENE DERIVATIVES DICATIONS CHEMISTRY ISOMERS C60 |
| ISSN号 | 1089-5639 |
| 通讯作者 | liu zy |
| 中文摘要 | the gas-phase ion-molecule reactions of c-60 with the methoxymethyl ion [ch3o=ch2](+) and the 1-hydroxyethyl ion [ch3ch=oh](+) generated under the self-chemical-ionization (self-ci) conditions of alkyl methyl ethers and primary alcohols were studied in the ion source of a mass spectrometer. the adduct ions [c60c2h5o](+) and protonated molecules [c60h](+) were observed as the major products of c-60 with the plasma of alkyl methyl ethers. on the contrary, the reactions of c-60 with the plasmas of primary alcohols produced few corresponding adduct ions. the am1 semiempirical molecular orbital calculations were carried out on 14 possible structures. the calculated results showed that the most stable structure among the possible isomers of [c60c2h5o](+) is the [3+2] cycloadduct. according to experimental and theoretical results, the pathway for the formation of the adduct was presented. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000083538100009 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/21549]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Ma L,Liu ZY,Wang WJ,et al. Gas-phase ion - Molecule reactions of neutral C-60 with the plasmas of alkyl methyl ethers and primary alcohols[J]. journal of physical chemistry a,1999,103(43):8634-8639. |
| APA | Ma L,Liu ZY,Wang WJ,Guo XH,&Liu SY.(1999).Gas-phase ion - Molecule reactions of neutral C-60 with the plasmas of alkyl methyl ethers and primary alcohols.journal of physical chemistry a,103(43),8634-8639. |
| MLA | Ma L,et al."Gas-phase ion - Molecule reactions of neutral C-60 with the plasmas of alkyl methyl ethers and primary alcohols".journal of physical chemistry a 103.43(1999):8634-8639. |
入库方式： OAI收割
来源：长春应用化学研究所
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