A manganese molybdenum phosphate with a tunnel: hydrothermal synthesis, structure and catalytic properties of (NH3CH2CH2NH3)(10-)H3O)(3)(H5O2)Na-2[MnMo12O24(OH)(6)(PO4)(4)(PO3OH)(4)]-[MnMo12O24(OH)(6)(PO4)(6)(PO3OH)(2)] center dot 9H(2)O
文献类型：期刊论文
| 作者 | Xu L ; Sun YQ ; Wang EB ; Shen EH ; Liu ZR ; Hu CW ; Xing Y ; Lin YH ; Jia HQ |
| 刊名 | new journal of chemistry
 |
| 出版日期 | 1999 |
| 卷号 | 23期号:10页码:1041-1044 |
| 关键词 | CRYSTAL-STRUCTURE HETEROPOLY BLUE |
| ISSN号 | 1144-0546 |
| 通讯作者 | wang eb |
| 中文摘要 | a manganese molybdenum phosphate, (nh3ch2ch2nh3)(10)(h3o)(3)(h5o)na-2[mnmo12o24(oh)(6) (po4)(4)(po3oh)(4)][mnmo12o24 (oh)(6)(po4)(6)(po3oh)(2)]. 9h(2)o, has been hydrothermally synthesized and structurally characterized by single crystal x-ray diffraction. the structure of this compound may be considered to be two [mo6o12(oh)(3)(po4)(2)(hpo4)(2)](7-) units bonded together by a manganese atom, although several p-o groups are not protonated on account of coordination to a na+ cation. one-dimensional tunnels were formed in the solid. a probe reaction of the oxidation of acetaldehyde with h2o2 using this compound as catalyst was carried out in a liquid-solid system, showing that the manganese molybdenum phosphate has high catalytic activity in the reaction. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000083439200016 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/21555]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Xu L,Sun YQ,Wang EB,et al. A manganese molybdenum phosphate with a tunnel: hydrothermal synthesis, structure and catalytic properties of (NH3CH2CH2NH3)(10-)H3O)(3)(H5O2)Na-2[MnMo12O24(OH)(6)(PO4)(4)(PO3OH)(4)]-[MnMo12O24(OH)(6)(PO4)(6)(PO3OH)(2)] center dot 9H(2)O[J]. new journal of chemistry,1999,23(10):1041-1044. |
| APA | Xu L.,Sun YQ.,Wang EB.,Shen EH.,Liu ZR.,...&Jia HQ.(1999).A manganese molybdenum phosphate with a tunnel: hydrothermal synthesis, structure and catalytic properties of (NH3CH2CH2NH3)(10-)H3O)(3)(H5O2)Na-2[MnMo12O24(OH)(6)(PO4)(4)(PO3OH)(4)]-[MnMo12O24(OH)(6)(PO4)(6)(PO3OH)(2)] center dot 9H(2)O.new journal of chemistry,23(10),1041-1044. |
| MLA | Xu L,et al."A manganese molybdenum phosphate with a tunnel: hydrothermal synthesis, structure and catalytic properties of (NH3CH2CH2NH3)(10-)H3O)(3)(H5O2)Na-2[MnMo12O24(OH)(6)(PO4)(4)(PO3OH)(4)]-[MnMo12O24(OH)(6)(PO4)(6)(PO3OH)(2)] center dot 9H(2)O".new journal of chemistry 23.10(1999):1041-1044. |
入库方式： OAI收割
来源：长春应用化学研究所
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