Novel macrocyclic aryl thioether ester oligomers: structure characterization and free-radical ring opening polymerization
文献类型：期刊论文
| 作者 | Qi YH ; Chen TL ; Jiang HY ; Bo SQ ; Xing Y ; Lin YH ; Xu JP |
| 刊名 | macromolecular chemistry and physics
 |
| 出版日期 | 1999 |
| 卷号 | 200期号:10页码:2407-2410 |
| 关键词 | AROMATIC DISULFIDE OLIGOMERS KETONE) MOIETY ROUTE |
| ISSN号 | 1022-1352 |
| 通讯作者 | chen tl |
| 中文摘要 | novel macrocyclic aryl thioether ester oligomers have been synthesized in high yield from phthaloyl dichloride and 4,4'-thiodiphenol under pseudo high dilution conditions. the cyclic nature was unambiguously confirmed by a combination of maldi-tof ms, gel permeation chromatography and nmr analyses. single-crystal x-ray diffraction of cyclic ester dimer reveals no severe strain on the cyclic structure. the free-radical ring opening polymerization (rop) of the macrocyclic oligomers was achieved to give high molecular weight polymers via a transthioetherification reaction. the molecular weight of the polymer resulting from rop decreases as the conversion of cyclic oligomers increases after a polymerization period of 30 min. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000083050000030 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/21579]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Qi YH,Chen TL,Jiang HY,et al. Novel macrocyclic aryl thioether ester oligomers: structure characterization and free-radical ring opening polymerization[J]. macromolecular chemistry and physics,1999,200(10):2407-2410. |
| APA | Qi YH.,Chen TL.,Jiang HY.,Bo SQ.,Xing Y.,...&Xu JP.(1999).Novel macrocyclic aryl thioether ester oligomers: structure characterization and free-radical ring opening polymerization.macromolecular chemistry and physics,200(10),2407-2410. |
| MLA | Qi YH,et al."Novel macrocyclic aryl thioether ester oligomers: structure characterization and free-radical ring opening polymerization".macromolecular chemistry and physics 200.10(1999):2407-2410. |
入库方式： OAI收割
来源：长春应用化学研究所
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