A mechanistic study of electrochemical oxidation processes of (OEP)Mg(II) in the presence of anions
文献类型：期刊论文
| 作者 | Wang ZX ; Liu DJ ; Lin XQ |
| 刊名 | chemical journal of chinese universities-chinese
 |
| 出版日期 | 1999 |
| 卷号 | 20期号:9页码:1442-1446 |
| 关键词 | RADICALS (TPP)CO |
| ISSN号 | 0251-0790 |
| 通讯作者 | lin xq |
| 中文摘要 | in the presence of f-, oh-, cl-, electrochemical redox of (oep)mg(ii) [2,3, 7,8,12,13,17,18 octaethyl-21h, 23h-porphine magnesium (ii)] are investigated in dce/0.1 mol/l solution by cyclic voltammetry and spectroelectrochemistry, in the presence of anions, anions are axially coordinated to (oep)mg(ii) generate (oep)mg(ii)y, the e-1/2 of (oep)ms(ii)y oxidation are negatively shifted. a chemical reaction following the second oxidation step is observed, the e-1/2 of the reaction product is obtained. mechanism of (oep)mg(ii) in the halogen and oh- anions titration process has been proposed. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 中文 |
| WOS记录号 | WOS:000082562400028 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/21641]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang ZX,Liu DJ,Lin XQ. A mechanistic study of electrochemical oxidation processes of (OEP)Mg(II) in the presence of anions[J]. chemical journal of chinese universities-chinese,1999,20(9):1442-1446. |
| APA | Wang ZX,Liu DJ,&Lin XQ.(1999).A mechanistic study of electrochemical oxidation processes of (OEP)Mg(II) in the presence of anions.chemical journal of chinese universities-chinese,20(9),1442-1446. |
| MLA | Wang ZX,et al."A mechanistic study of electrochemical oxidation processes of (OEP)Mg(II) in the presence of anions".chemical journal of chinese universities-chinese 20.9(1999):1442-1446. |
入库方式： OAI收割
来源：长春应用化学研究所
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