Using triazine as coupling unit for intramolecular ferromagnetic coupling of multiradicals
文献类型：期刊论文
| 作者 | Zhang JP ; Wang RS ; Wang LX ; Baumgarten M |
| 刊名 | chemical physics
 |
| 出版日期 | 1999 |
| 卷号 | 246期号:1-3页码:209-215 |
| 关键词 | ORGANIC DIRADICALS M-PHENYLENE POLYRADICALS |
| ISSN号 | 0301-0104 |
| 通讯作者 | zhang jp |
| 中文摘要 | novel high spin tri-, tetra-, pentaradicals, composed of triazine coupling units and cationic amino radical spin centers (+ . nh) under various configurations and linkages, are predicted from am1-ci calculations. it is found that for charged planar multiradicals the stability of high spin ground states depends on both the molecular configuration and the number of end groups. generally, cyclic 1,3-bridged charged multiradicals (s less than or equal to 5/2) possess more stable high spin ground states than their isomers under the branched 1,3,5,-bridged configuration. therefore, it is suggested that in the design of planar high spin molecules with stable high spin ground states, less end groups and all the supposed spin centers and/or the coupling units should be under the same structural situation. (c) 1999 elsevier science b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000082068600015 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/21689]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang JP,Wang RS,Wang LX,et al. Using triazine as coupling unit for intramolecular ferromagnetic coupling of multiradicals[J]. chemical physics,1999,246(1-3):209-215. |
| APA | Zhang JP,Wang RS,Wang LX,&Baumgarten M.(1999).Using triazine as coupling unit for intramolecular ferromagnetic coupling of multiradicals.chemical physics,246(1-3),209-215. |
| MLA | Zhang JP,et al."Using triazine as coupling unit for intramolecular ferromagnetic coupling of multiradicals".chemical physics 246.1-3(1999):209-215. |
入库方式： OAI收割
来源：长春应用化学研究所
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