Electrochemical behavior of a series of undecatungstozincates monosubstituted by first-row transition metals, ZnW11M(H2O)O-39(n-) (M = Cr, Mn, Fe, Co, Ni, Cu or Zn)
文献类型：期刊论文
| 作者 | Cheng L ; Sun H ; Liu BF ; Liu JF ; Dong SJ |
| 刊名 | journal of the chemical society-dalton transactions
 |
| 出版日期 | 1999 |
| 期号 | 15页码:2619-2625 |
| 关键词 | HIGH-VALENT MANGANESE POLYOXOMETALATE OXIDATION CATALYSTS DAWSON TYPE HETEROPOLYANIONS NON-POLAR SOLVENTS SUBSTITUTED HETEROPOLYTUNGSTATES ELECTROCATALYTIC REDUCTION ELECTRON-TRANSFER AQUEOUS-SOLUTION COMPLEXES NITRITE |
| ISSN号 | 0300-9246 |
| 通讯作者 | cheng l |
| 中文摘要 | the electrochemical behavior of a series of undecatungstozincates monosubstituted by first-row transition metals, znw11m(h2o)o-39(n-) (m=cr, mn, fe, co, ni, cu or zn), was investigated systematically and comparably in aqueous solutions by electrochemical and in situ uv-visible-near-ir spectroelectrochemical methods. these compounds exhibit not only successive reduction processes of the addenda atoms (w) in a negative potential range, but some of them also involve redox reactions originating from the substituted transition metals (m) such as the reduction of fe-iii and cu-ii at less negative potentials and the oxidation of mn-ii at a more positive potential. some interesting results and phenomena, especially of the transition metals, were found for the first time. moreover, possible reaction mechanisms are proposed based on the experimental results. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000081767900031 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/21699]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Cheng L,Sun H,Liu BF,et al. Electrochemical behavior of a series of undecatungstozincates monosubstituted by first-row transition metals, ZnW11M(H2O)O-39(n-) (M = Cr, Mn, Fe, Co, Ni, Cu or Zn)[J]. journal of the chemical society-dalton transactions,1999(15):2619-2625. |
| APA | Cheng L,Sun H,Liu BF,Liu JF,&Dong SJ.(1999).Electrochemical behavior of a series of undecatungstozincates monosubstituted by first-row transition metals, ZnW11M(H2O)O-39(n-) (M = Cr, Mn, Fe, Co, Ni, Cu or Zn).journal of the chemical society-dalton transactions(15),2619-2625. |
| MLA | Cheng L,et al."Electrochemical behavior of a series of undecatungstozincates monosubstituted by first-row transition metals, ZnW11M(H2O)O-39(n-) (M = Cr, Mn, Fe, Co, Ni, Cu or Zn)".journal of the chemical society-dalton transactions .15(1999):2619-2625. |
入库方式： OAI收割
来源：长春应用化学研究所
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