Processible nanostructured materials with electrical conductivity and magnetic susceptibility: Preparation and properties of maghemite polyaniline nanocomposite films
文献类型:期刊论文
作者 | Tang BZ ; Geng YH ; Lam JWY ; Li BS ; Jing XB ; Wang XH ; Wang FS ; Pakhomov AB ; Zhang XX |
刊名 | chemistry of materials
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出版日期 | 1999 |
卷号 | 11期号:6页码:1581-1589 |
关键词 | FINE PARTICLE SYSTEM LIQUID-CRYSTALLINE POLYACETYLENES MATRIX-MEDIATED SYNTHESIS NANOCRYSTALLINE GAMMA-FE2O3 NANOMETER-SIZE POLYPYRROLE IRON NANOPARTICLES COMPOSITES SOLVENTS |
ISSN号 | 0897-4756 |
通讯作者 | tang bz |
中文摘要 | we here present a versatile process for the preparation of maghemite/polyaniline (gamma-fe2o3/ pan) nanocomposite films with macroscopic processibility, electrical conductivity, and magnetic susceptibility. the gamma-fe2o3 nanoparticles are coated and the pan chains are doped by anionic surfactants of omega-methoxypoly(ethylene glycol) phosphate (peopa), 4-dodecylbenzenesulfonic acid (dbsa), and 10-camphorsulfonic acid (csa). both the coated gamma-fe2o3 and the doped pan are soluble in common organic solvents, and casting of the homogeneous solutions gives free-standing nanocomposite films with gamma-fe2o3 contents up to similar to 50 wt %. the morphology of the gamma-fe2o3 nanoparticles are characterized by transmission electron microscopy, uv-vis spectroscopy, and x-ray diffractometry. the gamma-fe2o3/pan films prepared from chloroform/m-cresol solutions of dbsa-coated gamma-fe2o3 and csa-doped pan are conductive (sigma = 82-237 s/cm) and superpapamagnetic, exhibiting no hysteresis at room temperature. the zero-field-cooled magnetization experiment reveals that the nanocomposite containing 20.8 wt % gamma-fe2o3 has a blocking temperature (t-b) in the temperature region of 63-83 k. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000080886100027 |
公开日期 | 2010-11-04 |
源URL | [http://202.98.16.49/handle/322003/21817] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Tang BZ,Geng YH,Lam JWY,et al. Processible nanostructured materials with electrical conductivity and magnetic susceptibility: Preparation and properties of maghemite polyaniline nanocomposite films[J]. chemistry of materials,1999,11(6):1581-1589. |
APA | Tang BZ.,Geng YH.,Lam JWY.,Li BS.,Jing XB.,...&Zhang XX.(1999).Processible nanostructured materials with electrical conductivity and magnetic susceptibility: Preparation and properties of maghemite polyaniline nanocomposite films.chemistry of materials,11(6),1581-1589. |
MLA | Tang BZ,et al."Processible nanostructured materials with electrical conductivity and magnetic susceptibility: Preparation and properties of maghemite polyaniline nanocomposite films".chemistry of materials 11.6(1999):1581-1589. |
入库方式: OAI收割
来源:长春应用化学研究所
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