Half-sandwich cyclopentandienyl molybdenum and tungsten nitrosyl complexes containing bidentate sulfur ligands
文献类型：期刊论文
| 作者 | Jin GX ; Herberhold M |
| 刊名 | transition metal chemistry
 |
| 出版日期 | 1999 |
| 卷号 | 24期号:3页码:317-320 |
| 关键词 | TRANSITION-METAL-COMPLEXES RAY CRYSTAL-STRUCTURES CHALCOGENIDO LIGANDS CHELATE LIGANDS INSERTION BOND CS2 |
| ISSN号 | 0340-4285 |
| 通讯作者 | jin gx |
| 中文摘要 | half-sandwich nitrosyl complexes cp*m(no)i-2 (m = mo, or w) react with dithiocarbamates (nas2cnme2 and nas2cnet2) in thf to form of complexes: cp*mo(no)i (s2cnme2) (1), cp*mo(no)i(s2cnet2) (2), cp*w(no)i(s2cnme2) (3) and cp*w(no)i(s2cnet2) (4) in high yields. treatments of cp*m(no)i-2 (m = mo, w) or [cpmo(no)i-2](2) with phosphinodithioate (nas2pme2) and phosphorodithioate [(nh4)s2p(ome)(2)] result in complexes: cp*mo(no)i(s2pme2) (5a), cpmo(no)i (s2pme2) (5b), cp*mo(no)(s2pme2)(2) (6a), cpmo (no) (s2pme2)(2) (6b) and cp*mo(no)i[s2p(ome)(2)] (7), cp*w(no)i(s2pme2) (8), cp*w(no) i[s2p(ome)](2) (9). treatment of (5a) and (5b) with an excess of nas2pme2 gives (6a) and (6b). the complexes have been characterized by their elemental analyses, i.r., h-1, c-13-n.m.r. and by ei-ms spectrometry. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000080544900014 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/21849]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Jin GX,Herberhold M. Half-sandwich cyclopentandienyl molybdenum and tungsten nitrosyl complexes containing bidentate sulfur ligands[J]. transition metal chemistry,1999,24(3):317-320. |
| APA | Jin GX,&Herberhold M.(1999).Half-sandwich cyclopentandienyl molybdenum and tungsten nitrosyl complexes containing bidentate sulfur ligands.transition metal chemistry,24(3),317-320. |
| MLA | Jin GX,et al."Half-sandwich cyclopentandienyl molybdenum and tungsten nitrosyl complexes containing bidentate sulfur ligands".transition metal chemistry 24.3(1999):317-320. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。