中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Crystal structure and drawing-induced polymorphism in poly(aryl ether ether ketone). IV

文献类型:期刊论文

作者Liu TX ; Wang SE ; Mo ZS ; Zhang HF
刊名journal of applied polymer science
出版日期1999
卷号73期号:2页码:237-243
关键词PHASE IDENTIFICATIONS PEEK MORPHOLOGY COPOLYMERS CRYSTALLIZATION PEKK
ISSN号0021-8995
通讯作者mo zs
中文摘要a new crystal modification induced by strain and denoted as form ii exists alongside the dominant form i structure in the uniaxially oriented poly(ether ether ketone) (peek) and the related polymers. the crystal structure of form ii for peek is also found to possess a two-chain orthorhombic packing with unit cell parameters of a equal to 0.475 nm, b equal to 1.060 nm, and c equal to 1.086 nm. more extended and flattened chain conformation of form ii relative to that of form i is expected to account for an 8% increase in c-axis dimension, which is attributed to the extensional deformation fixed in situ through strain-induced crystallization during uniaxial drawing. annealing experiments suggest that form ii is thermodynamically metastable and can be transformed into more stable form i by chain relaxation and reorganization at elevated temperature without external tension. this strain-induced polymorphism exists universally in the poly(aryl ether ketone) family. (c) 1999 john wiley & sons, inc.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000080296000010
公开日期2010-11-04
源URL[http://202.98.16.49/handle/322003/21887]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
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GB/T 7714
Liu TX,Wang SE,Mo ZS,et al. Crystal structure and drawing-induced polymorphism in poly(aryl ether ether ketone). IV[J]. journal of applied polymer science,1999,73(2):237-243.
APA Liu TX,Wang SE,Mo ZS,&Zhang HF.(1999).Crystal structure and drawing-induced polymorphism in poly(aryl ether ether ketone). IV.journal of applied polymer science,73(2),237-243.
MLA Liu TX,et al."Crystal structure and drawing-induced polymorphism in poly(aryl ether ether ketone). IV".journal of applied polymer science 73.2(1999):237-243.

入库方式: OAI收割

来源:长春应用化学研究所

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