The NMR-spectroscopic and X-ray crystal-structural characterization of two Cp*Ir halfsandwich complexes containing the 1,2-dicarba-closo-dodecaborane-1,2-diselenolato ligand
文献类型：期刊论文
| 作者 | Herberhold M ; Jin GX ; Yan H ; Milius W ; Wrackmeyer B |
| 刊名 | european journal of inorganic chemistry
 |
| 出版日期 | 1999 |
| 期号 | 5页码:873-875 |
| 关键词 | SE-77 NMR 1 SELENIUM 2-DITHIOLATE-O-CARBORANE |
| ISSN号 | 1434-1948 |
| 通讯作者 | herberhold m |
| 中文摘要 | the reaction of [cp*ircl2](2) with dilithium 1,2-orthocarborane-1,2-diselenolate 3 leads to the green 16-electron diselenolene complex [cp*ir{se2c2(b10h10)}] (4) which takes up two-electron ligands such as trimethylphosphane to give the 18-electron diselenolate derivative [cp*ir(pme3)-{se2c2(b10h10)}] (5). the molecular structures of 4 and 5 were determined by x-ray crystal structure analysis. the se-77-nuclear shielding in 4 is lower by almost 500 ppm relative to that in 5. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000080053900021 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/21901]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Herberhold M,Jin GX,Yan H,et al. The NMR-spectroscopic and X-ray crystal-structural characterization of two Cp*Ir halfsandwich complexes containing the 1,2-dicarba-closo-dodecaborane-1,2-diselenolato ligand[J]. european journal of inorganic chemistry,1999(5):873-875. |
| APA | Herberhold M,Jin GX,Yan H,Milius W,&Wrackmeyer B.(1999).The NMR-spectroscopic and X-ray crystal-structural characterization of two Cp*Ir halfsandwich complexes containing the 1,2-dicarba-closo-dodecaborane-1,2-diselenolato ligand.european journal of inorganic chemistry(5),873-875. |
| MLA | Herberhold M,et al."The NMR-spectroscopic and X-ray crystal-structural characterization of two Cp*Ir halfsandwich complexes containing the 1,2-dicarba-closo-dodecaborane-1,2-diselenolato ligand".european journal of inorganic chemistry .5(1999):873-875. |
入库方式： OAI收割
来源：长春应用化学研究所
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