Catalytic oxidization polymerization of aniline in an H2O2-Fe2+ system
文献类型：期刊论文
| 作者 | Sun ZC ; Geng YH ; Li J ; Wang XH ; Jing XB ; Wang FS |
| 刊名 | journal of applied polymer science
 |
| 出版日期 | 1999 |
| 卷号 | 72期号:8页码:1077-1084 |
| 关键词 | CHEMICAL POLYMERIZATION POLYANILINE EMERALDINE PERNIGRANILINE OXIDATION FORMS |
| ISSN号 | 0021-8995 |
| 通讯作者 | jing xb |
| 中文摘要 | polyaniline is prepared by chemical polymerization of aniline in an acidic solution using h2o2 as an oxidant and ferrous chloride as a catalyst. a wide variety of synthesis parameters are studied, such as the amount of the catalyst, reaction temperature, reaction time, initial molar ratio of oxidant, monomer and catalyst, and aniline and hcl concentrations. the polymerization of aniline can be initiated by a very small amount of catalyst. the yield and the conductivity of product depend on the initial molar ratio of the oxidant and monomer. the polyaniline with a conductivity of about 10 degrees s/cm and a yield of 60% is prepared under optimum conditions. the process of polymerization was studied by in situ ultraviolet-visible spectroscopy and open-circuit potential technology. compared to the polymerization process in a (nh4)(2)s2o8 system, the features of the h2o2-fe2+ system are pointed out, and the chain growth mechanism is proposed. (c) 1999 john wiley & sons, inc. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000079317300012 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/21975]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Sun ZC,Geng YH,Li J,et al. Catalytic oxidization polymerization of aniline in an H2O2-Fe2+ system[J]. journal of applied polymer science,1999,72(8):1077-1084. |
| APA | Sun ZC,Geng YH,Li J,Wang XH,Jing XB,&Wang FS.(1999).Catalytic oxidization polymerization of aniline in an H2O2-Fe2+ system.journal of applied polymer science,72(8),1077-1084. |
| MLA | Sun ZC,et al."Catalytic oxidization polymerization of aniline in an H2O2-Fe2+ system".journal of applied polymer science 72.8(1999):1077-1084. |
入库方式： OAI收割
来源：长春应用化学研究所
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